Organic photochemistry [electronic resource] : principles and applications / Jacques Kagan.
Organic Photochemistry outlines the principles, techniques and well-known reactions occurring in organic molecules and also illustrates more complex photochemical transformations occurring in organic chemistry. Many photochemical transformations convert simple molecules into extremely complex produc...
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| Format: | Electronic eBook |
| Language: | English |
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[Place of publication not identified] :
Academic Press,
1993.
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| 100 | 1 | |a Kagan, Jacques. |0 http://id.loc.gov/authorities/names/n83826751 |1 http://isni.org/isni/0000000082544837. | |
| 245 | 1 | 0 | |a Organic photochemistry |h [electronic resource] : |b principles and applications / |c Jacques Kagan. |
| 260 | |a [Place of publication not identified] : |b Academic Press, |c 1993. | ||
| 300 | |a 1 online resource. | ||
| 336 | |a text |b txt |2 rdacontent. | ||
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| 500 | |a Title from publisher supplied information (viewed November 15, 2012) | ||
| 504 | |a Includes bibliographical references and index. | ||
| 505 | 0 | |a Front Cover; Organic Photochemistry: Principles and Applications; Copyright Page; Table of Contents; Preface; Chapter 1. The fundamentals; 1.1. WHAT IS PHOTOCHEMISTRY?; 1.2. PHOTOCHEMISTRY: BASIC PRINCIPLES; 1.3. ACTION SPECTRA; 1.4. ABSORPTION OF LIGHT AND MOLECULAR ORBITALS; 1.5. SINGLET AND TRIPLET STATES OF MOLECULES; 1.6. FATE OF ELECTRONICALLY EXCITED MOLECULES; 1.7. MAKING INTERSYSTEM CROSSING MORE EFFICIENT: THE HEAVY-ATOM EFFECT; 1.8. TIME SCALE; 1.9. RELATIONSHIP BETWEEN WAVELENGTH AND PHOTON ENERGY; 1.10. UNITS; 1.11. BEER-LAMBERT'S LAW. | |
| 505 | 8 | |a 1.12. SOLVENT DEPENDENCE OF ABSORPTION SPECTRA SOLVATOCHROMIC DYES; 1.13. SOLVENT, TEMPERATURE, AND CONCENTRATION DEPENDENCE OF LUMINESCENCE SPECTRA; 1.14. WAVELENGTH DEPENDENCE OF PHOTOCHEMICAL REACTIONS; 1.15. QUANTUM YIELDS; 1.16. QUANTUM YIELDS AND CHEMICAL YIELDS; 1.17. ACTINOMETERS; 1.18. PHOTOSENSITIZED REACTIONS; 1.19. MECHANISTIC STUDIES; 1.20. PHOTOSENSITIZED REACTIONS OF A TRIPLET GROUND STATE MOLECULE; 1.21. EXPERIMENTAL CONSIDERATIONS FOR PHOTOSENSITIZED REACTIONS; 1.22. KINETICS; 1.23. ELECTRONICALLY EXCITED MOLECULES FROM DARK REACTIONS; 1.24. COMPLICATIONS. | |
| 505 | 8 | |a 1.25. RADICAL CATION AND RADICAL ANION FORMATION1.26. A COMMENT ON THE USE OF CIRCULARLY POLARIZED LIGHT; 1.27. PHOTOCHEMISTRY FROM HIGHER EXCITED STATES; REFERENCES; Chapter 2. Experimental techniques; 2.1. WARNING; 2.2. LIGHT SOURCES; 2.3. VESSELS; 2.4. STARTING AN EXPERIMENT; 2.5. MEDIUM; 2.6. SENSITIZED REACTIONS; REFERENCES; Chapter 3. Photochemistry of the carboncarbon double bond; 3.1. INTRODUCTION; 3.2. GEOMETRIC ISOMERIZATION; 3.3. CYCLOADDITION REACTIONS; 3.4. CYCLOREVERSION REACTIONS; 3.5. ISOMERIZATION REACTIONS: DOUBLE BOND SHIFTS. | |
| 505 | 8 | |a 4.4. VARIATIONS AND EMBELLISHMENTSREFERENCES; Chapter 5. Fragmentation reactions; 5.1. INTRODUCTION; 5.2. PHOTOHALOGENATION; 5.3. PHOTOLYSIS OF OTHER INORGANIC CHLORIDES; 5.4. PHOTOLYSIS OF ALKYL HALIDES; 5.5. PHOTOLYSIS OF N-HALOGENATED COMPOUNDS; 5.6. PHOTOLYSIS OF NITRITE ESTERS; 5.7. PHOTOLYSIS OF N-CHLORAMINES; 5.8. PHOTOLYSIS OF NITROAROMATIC COMPOUNDS; 5.9. PHOTOLYSIS OF AZO, DIAZO, AND AZIDE DERIVATIVES; 5 .10. OTHER FRAGMENTATION REACTIONS; REFERENCES; Chapter 6. Photochemistry with oxygen; 6.1. INTRODUCTION; 6.2. ELECTRONICALLY EXCITED FORMS OF OXYGEN; 6.3. DETECTION OF 1O2. | |
| 520 | |a Organic Photochemistry outlines the principles, techniques and well-known reactions occurring in organic molecules and also illustrates more complex photochemical transformations occurring in organic chemistry. Many photochemical transformations convert simple molecules into extremely complex products with an ease not approached by the standard synthetic chemistry practiced in the laboratory. In the earlier chapters, the author outlines the principles, techniques and some of the well-known reactions occurring in organic molecules and later illustrates more complex photochemical transformations occuring in organic chemistry. Experimental techniques are included to encourage novices. Topics are emphasized where structural transformations can be formulated chemically. Practical applications are collected together. The book starts at a comfortably simple level with enough examples to provide an introduction to the diversity of photochemical reactions. * Includes experimental techniques to encourage novices. * Emphasizes topics where structural transformations can be formulated chemically * Collects and presents practical applications * Written in a simple style including enough examples to serve as an introduction to the diversity of photochemical reactions. | ||
| 650 | 0 | |a Organic photochemistry. |0 http://id.loc.gov/authorities/subjects/sh88006157. | |
| 650 | 7 | |a Organic photochemistry. |2 fast |0 (OCoLC)fst01047721. | |
| 776 | 0 | 8 | |i Print version: |a Kagan, Jacques. |t Organic photochemistry. |d [Place of publication not identified] : Academic Press, 1993 |w (DLC) 93180458. |
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