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|a (TOE)ost1506174
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|a E 1.99:1506174
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|a E 1.99:1506174
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|a Atomically engineering activation sites onto metallic 1T-MoS<sub>2</sub> catalysts for enhanced electrochemical hydrogen evolution
|h [electronic resource]
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|a Washington, D.C. :
|b United States. Department of Energy. ;
|a Oak Ridge, Tenn. :
|b distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,
|c 2019.
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|a Article No. 982 (2019) :
|b digital, PDF file.
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|a text
|b txt
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|a computer
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|2 rdamedia.
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|a online resource
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|a Published through SciTech Connect.
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|a 02/28/2019.
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|a Nature Communications 10 1 ISSN 2041-1723 AM.
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|a Yichao Huang; Yuanhui Sun; Xueli Zheng; Toshihiro Aoki; Brian Pattengale; Jier Huang; Xin He; Wei Bian; Sabrina Younan; Nicholas Williams; Jun Hu; Jingxuan Ge; Ning Pu; Xingxu Yan; Xiaoqing Pan; Lijun Zhang; Yongge Wei; Jing Gu.
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|a Engineering catalytic sites at the atomic level provides an opportunity to understand the catalyst's active sites, which is vital to the development of improved catalysts. Here we show a reliable and tunable polyoxometalate template-based synthetic strategy to atomically engineer metal doping sites onto metallic 1T-MoS<sub>2</sub>, using Anderson-type polyoxometalates as precursors. Benefiting from engineering nickel and oxygen atoms, the optimized electrocatalyst shows great enhancement in the hydrogen evolution reaction with a positive onset potential of ̃ 0 V and a low overpotential of -46 mV in alkaline electrolyte, comparable to platinum-based catalysts. First-principles calculations reveal co-doping nickel and oxygen into 1T-MoS<sub>2</sub> assists the process of water dissociation and hydrogen generation from their intermediate states. This research will expand on the ability to improve the activities of various catalysts by precisely engineering atomic activation sites to achieve significant electronic modulations and improve atomic utilization efficiencies.
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|b AC02-76SF00515.
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|a Inorganic, Organic, Physical, And Analytical Chemistry.
|2 edbsc.
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| 710 |
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|a SLAC National Accelerator Laboratory.
|4 res.
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|a United States.
|b Department of Energy.
|4 spn.
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|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information.
|4 dst.
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|u http://www.osti.gov/scitech/biblio/1506174
|z Online Access (via OSTI)
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|a .b104700361
|b 03-09-23
|c 05-17-19
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|a web
|b 05-17-19
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|f eng
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|h 0
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|p Can circulate
|a University of Colorado Boulder
|b Online
|c Online
|d Online
|e E 1.99:1506174
|h Superintendent of Documents classification
|i web
|n 1
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