IR-IR Conformation Specific Spectroscopy of Na<sup>+</sup>(Glucose) Adducts [electronic resource]
Glucose; Spectroscopy; Conformers; Metal Ion.
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| Online Access: |
Online Access (via OSTI) |
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| Format: | Government Document Electronic eBook |
| Language: | English |
| Published: |
Washington, D.C. : Oak Ridge, Tenn. :
United States. Department of Energy. Office of Basic Energy Sciences ; distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,
2017.
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| Subjects: |
MARC
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| 245 | 0 | 0 | |a IR-IR Conformation Specific Spectroscopy of Na<sup>+</sup>(Glucose) Adducts |h [electronic resource] |
| 260 | |a Washington, D.C. : |b United States. Department of Energy. Office of Basic Energy Sciences ; |a Oak Ridge, Tenn. : |b distributed by the Office of Scientific and Technical Information, U.S. Department of Energy, |c 2017. | ||
| 300 | |a p. 42-50 : |b digital, PDF file. | ||
| 336 | |a text |b txt |2 rdacontent. | ||
| 337 | |a computer |b c |2 rdamedia. | ||
| 338 | |a online resource |b cr |2 rdacarrier. | ||
| 500 | |a Published through SciTech Connect. | ||
| 500 | |a 09/27/2017. | ||
| 500 | |a ": 1813" | ||
| 500 | |a Journal of the American Society for Mass Spectrometry 29 1 ISSN 1044-0305 AM. | ||
| 500 | |a Jonathan M. Voss; Steven J. Kregel; Kaitlyn C. Fischer; Etienne Garand. | ||
| 520 | 3 | |a Here in this paper we report an IR-IR double resonance study of the structural landscape present in the Na<sup>+</sup>(glucose) complex. Our experimental approach involves minimal modifications to a typical IR predissociation setup, and can be carried out via ion-dip or isomer-burning methods, providing additional flexibility to suit different experimental needs. In the current study, the single-laser IR predissociation spectrum of Na<sup>+</sup>(glucose), which clearly indicates contributions from multiple structures, was experimentally disentangled to reveal the presence of three α-conformers and five β-conformers. Comparisons with calculations show that these eight conformations correspond to the lowest energy gas-phase structures with distinctive Na+ coordination. | |
| 520 | 0 | |a Glucose; Spectroscopy; Conformers; Metal Ion. | |
| 536 | |b SC0010326. | ||
| 536 | |b CHE-0840494. | ||
| 650 | 7 | |a Inorganic, Organic, Physical, And Analytical Chemistry. |2 edbsc. | |
| 710 | 2 | |a University of Wisconsin--Madison. |4 res. | |
| 710 | 1 | |a United States. |b Department of Energy. |b Office of Basic Energy Sciences. |4 spn. | |
| 710 | 2 | |a National Science Foundation (U.S.). |4 spn. | |
| 710 | 1 | |a United States. |b Department of Energy. |b Office of Scientific and Technical Information. |4 dst. | |
| 856 | 4 | 0 | |u http://www.osti.gov/scitech/biblio/1425956 |z Online Access (via OSTI) |
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| 952 | f | f | |p Can circulate |a University of Colorado Boulder |b Online |c Online |d Online |e E 1.99:1425956 |h Superintendent of Documents classification |i web |n 1 |