The ?-phase superconductors Nb<sub>20.4</sub>Rh<sub>5.7</sub>Ge<sub>3.9</sub> and Nb<sub>20.4</sub>Rh<sub>5.7</sub>Si<sub>3.9</sub> [electronic resource]

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Published: Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Department of Energy, 2018.
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245 0 4 |a The ?-phase superconductors Nb<sub>20.4</sub>Rh<sub>5.7</sub>Ge<sub>3.9</sub> and Nb<sub>20.4</sub>Rh<sub>5.7</sub>Si<sub>3.9</sub>  |h [electronic resource] 
260 |a Oak Ridge, Tenn. :  |b Distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,  |c 2018. 
300 |a Size: p. 96-101 :  |b digital, PDF file. 
336 |a text  |b txt  |2 rdacontent. 
337 |a computer  |b c  |2 rdamedia. 
338 |a online resource  |b cr  |2 rdacarrier. 
500 |a Published through Scitech Connect. 
500 |a 09/20/2018. 
500 |a "Journal ID: ISSN 0038-1098" 
500 |a Carnicom, Elizabeth M. ; Kong, Tai ; Klimczuk, Tomasz ; Cava, R. J. ;  
500 |a Princeton Univ., NJ (United States) 
500 |a USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) 
500 |a Gordon and Betty Moore Foundation. 
500 |a National Science Centre. 
520 3 |a We show that the previously unreported ternary ? phases Nb<sub>20.4</sub>Rh<sub>5.7</sub>Ge<sub>3.9</sub> and Nb<sub>20.4</sub>Rh<sub>5.7</sub>Si<sub>3.9</sub> are both superconductors with T<sub>c</sub> values of approximately 1.9 K. The superconducting transitions were characterized through temperature-dependent magnetic susceptibility, electrical resistance, and specific heat measurements. The Sommerfeld constants, ?, for Nb<sub>20.4</sub>Rh<sub>5.7</sub>Ge<sub>3.9</sub> and Nb<sub>20.4</sub>Rh<sub>5.7</sub>Si<sub>3.9</sub> are 89(1) mJ mol-f.u.<sup>?1</sup>K<sup>?2</sup> and 86(1) mJ mol-f.u.<sup>?1</sup>K<sup>?2</sup> (about 3.0 and 2.9 mJ mol-atom<sup>?1</sup> K<sup>?2</sup>), respectively. Here, the normalized specific heat jumps at T<sub>c</sub>, ?C/?T<sub>c</sub>, are approximately 1.39 for Nb<sub>20.4</sub>Rh<sub>5.7</sub>Ge<sub>3.9</sub> and 1.30 for Nb<sub>20.4</sub>Rh<sub>5.7</sub>Si<sub>3.9</sub>, consistent with both materials being weakly coupled BCS type superconductors. 
536 |b FG02-98ER45706. 
536 |b GBMF-4412. 
536 |b UMO-2016/22/M/ST5/00435. 
650 7 |a 75 condensed matter physics, superconductivity and superfluidity  |2 local. 
650 7 |a Sigma phases  |2 local. 
650 7 |a Disorder  |2 local. 
650 7 |a Superconductivity  |2 local. 
650 7 |a Arc-melting  |4 spn  |4 spn  |4 spn  |2 local. 
710 1 |a United States.  |b Department of Energy.  |b Office of Scientific and Technical Information  |4 dst. 
856 4 0 |u http://www.osti.gov/servlets/purl/1595070  |z Full Text (via OSTI) 
907 |a .b110133687  |b 11-30-21  |c 05-11-20 
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952 f f |p Can circulate  |a University of Colorado Boulder  |b Online  |c Online  |d Online  |i web  |n 1