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|a Intercalated water in aqueous batteries
|h [electronic resource]
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|a Washington, D.C. :
|b United States. Office of Under Secretary of Energy for Energy and Environment ;
|a Oak Ridge, Tenn. :
|b Distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,
|c 2020.
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| 300 |
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|a Size: p. 251-264 :
|b digital, PDF file.
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|a text
|b txt
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|a online resource
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|a Published through Scitech Connect.
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|a 05/29/2020.
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|a "pnnl-sa-152333."
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|a "Journal ID: ISSN 2637-9368."
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|a Xiao, Biwei ;
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|a The unprecedentedly growing demand for energy storage devices in recent years calls for diversified chemistries with unique advantages. When it comes to safety and cost, aqueous battery systems have attracted tremendous attention. Being a universal solvent, water can solvate the cations with rather high dehydration energy due to the hydrogen bonding environment, relatively small size and high polarity. Such properties make solvent co-intercalation, which is seen in a few of the non-aqueous systems, more likely to happen in aqueous batteries. Hydrated cations show drastically different behaviors from naked cations during intercalation/de-intercalation processes and hence enable many reactions that are otherwise difficult to proceed. This review summarizes the roles of co-intercalated water in aqueous batteries from how water molecules coordinate with cations to examples of water-mediated reactions in different types of host materials.
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|b AC05-76RL01830.
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|b 70247A.
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|a Aqueous batteries
|2 local.
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|a Hydrated cation
|2 local.
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|a Intercalation
|2 local.
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|a Water
|2 local.
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|a Pacific Northwest National Laboratory (U.S.).
|4 res.
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|a United States. Office of Under Secretary of Energy for Energy and Environment.
|4 spn.
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|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information
|4 dst.
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|u https://www.osti.gov/servlets/purl/1737353
|z Full Text (via OSTI)
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|c 01-28-21
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|a University of Colorado Boulder
|b Online
|c Online
|d Online
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