C-H and C-X bond functionalization [electronic resource] : transition metal mediation / edited by Xavi Ribas.
Cross-coupling reactions involving C-H and C-X bond functionalisation are commonplace in natural product synthesis and natural products, therapeutic agents, biological probes, and advanced materials. Much attention has been given to understanding the mechanistic strategies used to achieve this, maki...
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| Format: | Electronic eBook |
| Language: | English |
| Published: |
Cambridge :
Royal Society of Chemistry,
2013.
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| Series: | RSC catalysis series.
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Table of Contents:
- 1. Cu-catalyzed Ullmann-type C-heteroatom bond formation: the key role of dinucleating ancillary ligands; 2. Mechanistic understanding of copper-catalyzed aryl-heteroatom bond formation: dependence on ancillary ligands; 3. Fundamental Pd(0)/Pd(II) redox steps in cross-coupling reactions; 4. Pd(II)/Pd(IV) redox catalysis for C-heteroatom bond formation; 5. Mononuclear and Dinuclear Organometallic PdIII complexes in C-C and C-heteroatom bond formation reactions; 6. Aromatic C-F activation: converting toxic substrates to useful synthons; 7. Strategies towards challenging aromatic fluorination and trifluoromethylation reactions; 8. Coordination-directed metallation strategy for C-H functionalization; 9. Transition-metal-catalyzed direct arylation of unactivated arenes with aryl Halides; 10. Double C-H activation in Pd-catalyzed cross-coupling reactions of non-preactivated arenes; 11. Palladium and copper-catalyzed oxidation of organic chemicals; 12. Strategies for metal-mediated direct arylation of nucleosides and amino acid derivatives.