Pillararenes / editor: Tomoki Ogoshi.
First reported in 2008, Pillararenes are a new class of macrocyclic hosts consisting of hydroquinone units linked at the para-position. With a composition similar to cucurbiturils and calixarenes, they combine the advantages and aspects of traditional hosts and have applications in sensing, material...
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| Format: | eBook |
| Language: | English |
| Published: |
[Cambridge] :
Royal Society of Chemistry,
[2015]
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| Series: | Monographs in supramolecular chemistry ;
18. |
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Table of Contents:
- Cover; Contents; Preface; Chapter 1 Historical Background of Macrocyclic Compounds; 1.1 Introduction; 1.2 Cyclodextrins; 1.3 Crown Ethers and Their Derivatives; 1.4 Calix[n]arenes and Their Derivatives; 1.5 Cucurbit[n]urils CB[n] and Their Derivatives; 1.6 Other Synthetic Macrocyclic Compounds; 1.7 Conclusion and Outlook; References; Chapter 2 Synthesis of Pillar[n]arenes; 2.1 Introduction; 2.2 Synthesis of Pillar[5] arenes; 2.2.1 Synthesis of Pillar[5]arene from 1,4-Dimethoxybenzene as a Monomer; 2.2.2 Synthesis of Pillar[5]arenes from 1,4-Dialkoxybenzene Monomers.
- 2.2.3 Mechanism of the Formation of Pillar[5]arenes
- Thermodynamic Control2.3 Synthesis of Pillar[6]arenes under Kinetic and Thermodynamic Control; 2.4 Synthesis of Larger Pillar[n]arene Homologs under Kinetic Control; 2.5 Conclusion and Outlook; References; Chapter 3 Functionalization of Pillararenes; 3.1 Introduction; 3.2 Per-functionalization of Pillar[n]arenes by Pre-formed Pillar[n]arenes; 3.3 Per-functionalization of Pillar[n]arenes by Cyclization of Dialkoxybenzene Derivatives with Reactive Moieties; 3.4 Mono-functionalization of Pillar[5]- and Pillar[6]arenes.
- 3.5 Di-functionalized Pillar[5]- and Pillar[6]arenes3.6 Functionalized Pillar[5] arenes with More Than Three Diifferent Substituents; 3.7 Conclusion and Outlook; References; Chapter 4 Conformation and Planar Chirality of Pillar[n]arenes; 4.1 Introduction; 4.2 Conformation of Pillar[5]arenes; 4.2.1 Conformation of Pillar[5]arenes with Simple Alkyl Substituents; 4.2.2 Conformation of Pillar[5]arenes with One p-Conjugated Unit; 4.2.3 Conformation of Hydroxylated Pillar[5]arenes; 4.2.4 Conformation of Non-symmetrical Pillar[5]arenes; 4.3 Conformations of Pillar[6]arenes.
- 4.3.1 Conformation of Symmetrical Per-alkylated Pillar[6]arenes4.3.2 Conformation of Per-hydroxylated Pillar[6]arene; 4.4 Conclusion and Outlook; References; Chapter 5 Host-Guest Properties of Pillar[n]arenes; 5.1 Introduction; 5.2 X-ray Crystal Structure and Electron Potential Profiles of Pillar[n]arenes; 5.3 Host-Guest Properties of Pillar[5]arenes; 5.3.1 per-Hydroxylated Pillar[5]arene; 5.3.2 per-Alkylated Pillar[5]arenes; 5.3.3 Water-soluble Pillar[5]arenes; 5.3.4 Functionalized Pillar[5]arenes; 5.4 Host-Guest Properties of Pillar[6]arenes; 5.4.1 per-Hydroxylated Pillar[6]arene.
- 5.4.2 per-Alkylated Pillar[6]arenes5.4.3 Water-soluble Pillar[6]arenes; 5.4.4 Functionalized Pillar[6]arenes; 5.5 Host-Guest Properties of LargerPillar[n]arene Homologs (n = 7-14); 5.6 Summary and Outlook; References; Chapter 6 Assembled Structures of Pillar[n]arenes; 6.1 Introduction; 6.2 Assembled Structures of Pillar[5]arenes in Crystal States; 6.2.1 per-Alkylated Pillar[5]arenes; 6.2.2 per-Functionalized Pillar[5]arenes; 6.2.3 A1/A2 Pillar[5]arenes; 6.2.4 Pillar[5]arenes with Two and Three Benzoquinone Units; 6.2.5 Non-symmetrical Pillar[5]arenes.