Nitroxide mediated polymerization : from fundamentals to applications in materials science / editor: Didier Gigmes.
Nitroxide-mediated polymerization is an important branch of controlled radical polymerization, which has revolutionised the preparation of polymer architectures and compositions. This is the first book dedicated to the topic and covers the history and development of nitroxide-mediated polymerization...
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Full Text (via RSC) |
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| Format: | eBook |
| Language: | English |
| Published: |
[Cambridge] :
Royal Society of Chemistry,
[2015]
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| Series: | RSC polymer chemistry series ;
19. |
| Subjects: |
Table of Contents:
- Cover; Contents; Preface; Chapter 1 The History of Nitroxide-mediated Polymerization; 1.1 Introduction; 1.2 Radical Polymerization; 1.3 Initiation Mechanisms in Radical Polymerization by Radical Trapping; 1.4 First Examples of Nitroxide-mediated Polymerization; 1.4.1 Homopolymer Synthesis; 1.4.2 Block Copolymer Synthesis; 1.4.3 Graft Copolymer Synthesis; 1.4.4 Effects of Alkoxyamine Structure and Polymerization Conditions on Homolysis Rates; 1.4.5 End-group Removal; 1.5 Developments in NMP 1993-2000; 1.5.1 Xerox Group; 1.5.2 Hawker Group; 1.5.3 Fukuda Group; 1.5.4 Fischer Group.
- 1.5.5 Other Groups1.6 Conclusions; References; Chapter 2 Kinetic Aspects of Nitroxide Mediated Polymerization; 2.1 Nitroxide Mediated Polymerization (NMP) and Key Reactions that Determine its Kinetics; 2.1.1 Persistent Radical Effect (PRE) and its Application for NMP; 2.1.2 Equations for NMP and the Phase Diagram Approach; 2.1.3 Evidence of the Occurrence of PRE in NMP; 2.1.4 Importance of kc; 2.1.5 Importance of kd; 2.1.6 Importance of the Initiation Stage; 2.1.7 Importance of the Side-reactions on the Fate of NMP; 2.2 Recombination of Nitroxides and Alkyl Radicals.
- 2.2.1 Techniques and Methods of Determination2.2.2 Arrhénius Parameters; 2.2.3 Effects Influencing kc; 2.3 The C-ON Bond Homolysis of Alkoxyamines; 2.3.1 Techniques and Methods of Determination; 2.3.2 Arrhénius Parameters; 2.3.3 Effects Influencing kd; 2.3.4 Other Types of Activation; 2.4 Conclusion and Outlook; Acknowledgments; References; Chapter 3 Synthesis of Nitroxides and Alkoxyamines; 3.1 Introduction; 3.1.1 General Considerations; 3.1.2 Nitroxide Preparation; 3.1.3 Nitroxide Design; 3.2 Synthesis of Alkoxyamines; 3.2.1 General Considerations; 3.2.2 Alkoxyamine Preparation.
- 3.3 ConclusionsReferences; Chapter 4 NMP Under Homogenous Conditions in Bulk, Organic Solvents and Aqueous Systems; 4.1 Introduction; 4.2 Bulk NMP; 4.2.1 Homopolymerizations by Bulk NMP with TEMPO; 4.2.2 Bulk NMP with TEMPO-derived Initiators; 4.2.3 Bulk NMP with TIPNO; 4.2.4 Bulk NMP with SG1; 4.3 NMP in Organic Solvents; 4.3.1 NMP with TEMPO in Organic Solvents; 4.3.2 NMP with TIPNO in Organic Solvents; 4.3.3 NMP with SG1 in Organic Solvents; 4.4 NMP in Aqueous Solutions; 4.5 Conclusions and Outlook; References; Chapter 5 Nitroxide-mediated Polymerization in Dispersed Media.
- 5.1 Introduction5.2 Nitroxide-mediated (Mini)Emulsion Polymerization; 5.2.1 Brief Account of Free-radical Polymerization in Miniemulsion and Emulsion; 5.2.2 Challenges to Overcome; 5.2.3 NMP in Miniemulsion; 5.2.4 NMP in Emulsion; 5.2.5 NMP in Microemulsion; 5.2.6 Compartmentalization Effects; 5.3 Nitroxide-mediated Dispersion Polymerization; 5.3.1 Dispersion Polymerization in Common Solvents; 5.3.2 Dispersion Polymerization in Supercritical Carbon Dioxide (scCO2); 5.4 Nitroxide-mediated Precipitation Polymerization; 5.5 Nitroxide-mediated Suspension Polymerization; 5.6 Conclusion; References.