Asymmetric synthesis. II [electronic resource] : more methods and applications / edited by Mathias Christmann and Stefan Bräse.
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| Other title: | Asymmetric synthesis II. Asymmetric synthesis 2. Asymmetric synthesis : more methods and applications. |
| Format: | Electronic eBook |
| Language: | English |
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Weinheim, Germany :
Wiley-VCH Verlag & Co. KGaA,
2013.
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| Edition: | First edition. |
| Subjects: |
MARC
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| 245 | 0 | 0 | |a Asymmetric synthesis. |n II |h [electronic resource] : |b more methods and applications / |c edited by Mathias Christmann and Stefan Bräse. |
| 246 | 3 | |a Asymmetric synthesis II. | |
| 246 | 3 | |a Asymmetric synthesis 2. | |
| 246 | 3 | 0 | |a Asymmetric synthesis : |b more methods and applications. |
| 250 | |a First edition. | ||
| 264 | 1 | |a Weinheim, Germany : |b Wiley-VCH Verlag & Co. KGaA, |c 2013. | |
| 264 | 4 | |c ©2012. | |
| 300 | |a 1 online resource (xxvi, 404 pages) : |b illustrations. | ||
| 336 | |a text |b txt |2 rdacontent. | ||
| 337 | |a computer |b c |2 rdamedia. | ||
| 338 | |a online resource |b cr |2 rdacarrier. | ||
| 500 | |a "Published Online: 14 JAN 2013"--Home page. | ||
| 500 | |a Edition statement from first page of chapter PDFs. | ||
| 504 | |a Includes bibliographical references and index. | ||
| 505 | 0 | |6 880-01 |a Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates / Corey M Reeves, Brian M Stoltz -- Point-to-Planar Chirality Transfer in Total Synthesis: Scalable and Programmable Synthesis of Haouamine A and Its Atropisomer / Noah Z Burns, Phil S Baran -- Tethered Aminohydroxylation / Timothy J Donohoe, Stefanie Mesch -- Organocatalyzed Transformations of [alpha], [beta]-Unsaturated Carbonyl Compounds through Iminium Ion Intermediates / Julian H Rowley, Nicholas C O Tomkinson -- The Renaissance of Silicon-Stereogenic Silanes: A Personal Account / Andreas Weickgenannt, Martin Oestreich -- Asymmetric Dienamine Activation / Mathias Christmann -- Asymmetric Bronsted Acid Catalysis / Iuliana Atodiresei, Uxue Uria, Magnus Rueping -- Quaternary Stereogenic Centers by Enantioselective [beta]-Carbon Eliminations from tert-Cyclobutanols / Nicolai Cramer, Tobias Seiser -- Total Synthesis of Oseltamivir and ABT-341 Using One-Pot Technology / Hayato Ishikawa, Yujiro Hayashi -- Enantioselective Annulations with Chiral N-Mesityl N-Heterocyclic Carbenes / Jessada Mahatthananchai, Jeffrey W Bode -- Asymmetric Counteranion-Directed Catalysis (ACDC) / Manuel Mahlau, Benjamin List -- Enantioselective Organo-SOMO Catalysis: a Novel Activation Mode for Asymmetric Synthesis / David W C Macmillan, Sebastian Rendler -- Enantioselective Passerini Reaction / Qian Wang, Jieping Zhu, Mei-Xiang Wang -- Rapid Enantiomeric Excess Determination / Oliver Trapp -- Asymmetric Catalysis of Reversible Reactions / Lukas Hintermann -- Exploiting Fluorine Conformational Effects in Organocatalyst Design: The Fluorine-Iminium Ion / Christof Sparr, Lucie E Zimmer, Ryan Gilmour -- Dutch Resolution / Richard M Kellogg -- Construction of anti-Me-OH Vicinal Relationships in Polyketides / Vaidotas Navickas, Martin E Maier -- Photoswitchable General Base Catalysts / Philipp Viehmann, Stefan Hecht -- Asymmetric Halonium Addition to Olefins / Scott A Snyder, Alexandria P Brucks -- Catalytic Asymmetric Gosteli-Claisen Rearrangement (CAGC) / Julia Rehbein, Martin Hiersemann -- Biomimetic Total Synthesis of the Penifulvin Family / Tanja Gaich, Johann Mulzer -- Catalyst-Controlled 1,3-Polyol Syntheses / Tobias Harschneck, Stefan F Kirsch -- Enantioselective Carbonyl Allylation and Crotylation from the Alcohol Oxidation Level via C-C Bond Forming Transfer Hydrogenation / Joseph Moran, Michael J Krische -- Stereoselective Synthesis with Hypervalent Iodine Reagents / Umar Farid, Thomas Wirth -- Asymmetric Gold-Catalyzed Reactions / Nuria Huguet, Antonio M Echavarren -- Asymmetric Catalysis in the Total Synthesis of Lipids and Polyketides / Santiago Barroso, Adriaan J Minnaard -- The Evolving Role of Biocatalysis in Asymmetric Synthesis / Meelanie Hall, Wolfgang Kroutil, Kurt Faber -- Bifunctional Thiourea Catalysts / Yoshiji Takemoto, Tsubasa Inokuma -- Catalytic Asymmetric (4 + 3) Cycloadditions Using Allenamides / Yun-Fei Du, Richard P Hsung -- Application of the Achmatowicz Rearrangement for the Synthesis of Oligosaccharides / Michael F Cuccarese, George A O'doherty -- Asymmetric C-C Bond Formation Using Chiral Phosphoric Acid / Takahiko Akiyama -- Asymmetric C-H Bond Functionalization / Masayuki Wasa, Kelvin S L Chan, Jin-Quan Yu -- Asymmetric C-C Bond Formation Using Chiral Guanidine Catalysts / Masahiro Terada -- Enantioselective Synthesis of Lactones via Rh-Catalyzed Ketone Hydroacylation / Matthew M Coulter, Vy M Dong -- Radical Haloalkylation / Armen Zakarian -- Asymmetric Hydrovinylation of Alkenes / T V (babu) Rajanbabu -- Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions / Kevin M Oberg, Tomislav Rovis -- N-Heterocyclic Carbene-Catalyzed Aldol Desymmetrizations / Karl A Scheidt, Eric M Phillips, Julien Dugal-Tessier -- Strategies for the Asymmetric Total Synthesis of Natural Products: "Chiral Pool" versus Chiral Catalysts / Karl Gademann -- Dynamic Kinetic Asymmetric Transformations Involving Carbon-Carbon Bond Cleavage / Andrew T Parsons, Jeffrey S Johnson -- Iron-Catalyzed Allylic Substitutions / Markus Jegelka, Bernd Plietker -- Asymmetric Conia-ene Carbocyclizations / Filippo Sladojevich, Darren J Dixon -- Tactics and Strategies in the Total Synthesis of Chlorosulfolipids / Christian Nilewski, Erick M Carreira -- Linear Free Energy Relationships (LFERs) in Asymmetric Catalysis / Elizabeth N Bess, Matthew S Sigman -- Asymmetric Diamination of Alkenes / Jose A Souto, Kilian Muniz -- Enzymatic Asymmetric Synthesis of Tertiary Alcohols / Michael Richter -- Oxidative Dearomatization and Organocatalytic Desymmetrization / Alice E Williamson, Matthew J Gaunt -- Total Synthesis of All ( -- )-Agelastatin Alkaloids / Mohammad Movassaghi, Sunkyu Han. | |
| 520 | 3 | |a After the overwhelming success of 'Asymmetric Synthesis - The Essentials', narrating the colorful history of asymmetric synthesis, this is the second edition with latest subjects and authors. While the aim of the first edition was mainly to honor the achievements of the pioneers in asymmetric syntheses, the aim of this new edition was bringing the current developments, especially from younger colleagues, to the attention of students. The format of the book remained unchanged, i.e. short conceptual overviews by young leaders in their field including a short biography of the authors. The growing multidisciplinary research within chemistry is reflected in the selection of topics including metal catalysis, organocatalysis, physical organic chemistry, analytical chemistry, and its applications in total synthesis. The prospective reader of this book is a graduate or undergraduate student of advanced organic chemistry as well as the industrial chemist who wants to get a brief update on the current developments in the field. | |
| 588 | 0 | |a Online resource; title from home page (viewed July 22, 2014) | |
| 650 | 0 | |a Asymmetric synthesis. |0 http://id.loc.gov/authorities/subjects/sh92006333. | |
| 650 | 7 | |a Asymmetric synthesis. |2 fast |0 (OCoLC)fst00819861. | |
| 700 | 1 | |a Christmann, Mathias. |0 http://id.loc.gov/authorities/names/nb2006026639 |1 http://isni.org/isni/0000000117457662. | |
| 700 | 1 | |a Bräse, Stefan. |0 http://id.loc.gov/authorities/names/nb2006026640 |1 http://isni.org/isni/0000000115677442. | |
| 776 | 0 | 8 | |i Print version: |t Asymmetric synthesis II. |d Weinheim : Wiley-VCH, ©2012 |z 9783527329212 |w (OCoLC)821678444. |
| 856 | 4 | 0 | |u https://colorado.idm.oclc.org/login?url=https://onlinelibrary.wiley.com/doi/book/10.1002/9783527652235 |z Full Text (via Wiley) |
| 880 | 0 | 0 | |6 505-00/(S |g Machine generated contents note: |g 1. |t Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates / |r Brian M. Stoltz -- |t Background -- |t Strategy and Results -- |t Asymmetric Allylic Alkylation in Total Synthesis -- |t Conclusions -- |t CV of Corey M. Reeves -- |t CV of Brian M. Stoltz -- |t References -- |g 2. |t Point-to-Planar Chirality Transfer in Total Synthesis: Scalable and Programmable Synthesis of Haouamine A and Its Atropisomer / |r Phil S. Baran -- |t Introduction -- |t Synthetic Strategy Featuring Point-to-Planar Chirality Transfer -- |t Programmable Synthesis of Haouamine A and Its Atropisomer -- |t CV of Noah Z. Burns -- |t CV of Phil S. Baran -- |t References -- |g 3. |t Tethered Aminohydroxylation / |r Stefanie Mesch -- |t Introduction and Background -- |t Tethered Aminohydroxylation -- |g a). |t First Generation of Reoxidants -- |g b). |t N-Sulfonyloxy Carbamates -- |g c). |t Carbonyloxycarbamates as Reoxidants for Osmium -- |t Amide-Based Reoxidants -- |t Evidence for the Mechanism of the TA Reaction -- |t Applications in Organic Synthesis -- |t Conclusion and Future Work -- |t CV of Timothy J. Donohoe -- |t CV of Stefanie Mesch -- |t References -- |g 4. |t Organocatalyzed Transformations of α, β-Unsaturated Carbonyl Compounds through Iminium Ion Intermediates / |r Nicholas C.O. Tomkinson -- |t CV of Nicholas C.O. Tomkinson -- |t CV of Julian H. Rowley -- |t References -- |g 5. |t Renaissance of Silicon-Stereogenic Silanes: A Personal Account / |r Martin Oestreich -- |t Background -- |t Results -- |g a). |t Intermolecular Chirality Transfer from Silicon to Carbon: Diastereoselective Palladium(II)-Catalyzed C--Si Bond Formation -- |g b). |t Silicon-Stereogenic Silane as Stereochemical Probe: B(C6F5)3-Catalyzed Carbonyl Reduction -- |g c). |t Kinetic Resolution with Silicon-Stereogenic Silanes: Cu--H-Catalyzed Diastereoselective Si--O Coupling -- |t Conclusion -- |t CV of Martin Oestreich -- |t CV of Andreas Weickgenannt -- |t References -- |g 6. |t Asymmetric Dienamine Activation / |r Mathias Christmann -- |t Introduction -- |t Historic Background -- |t Results -- |t Conclusion -- |t CV of Mathias Christmann -- |t References -- |g 7. |t Asymmetric Brønsted Acid Catalysis / |r Magnus Rueping -- |t Introduction and Background -- |t Strategy -- |t Results -- |t Summary -- |t CV of Iuliana Atodiresei -- |t CV of Uxue Uria -- |t CV of Magnus Rueping -- |t References -- |g 8. |t Quaternary Stereogenic Centers by Enantioselective β-Carbon Eliminations from tert-Cyclobutanols / |r Tobias Seiser -- |t Background -- |t Objective: Enantioselective Formation of Quaternary Stereogenic Centers in Combination with Reactive Alkyl-Rhodium Intermediates -- |t Selective Generation of the Alkyl-Rhodium Species and Its Downstream Reactivities -- |t CV of Nicolai Cramer -- |t CV of Tobias Seiser -- |t References -- |g 9. |t Total Synthesis of Oseltamivir and ABT-341 Using One-Pot Technology / |r Yujiro Hayashi -- |t Introduction -- |t Results -- |g a). |t Total Synthesis of ( --- )-Oseltamivir via Two One-Pot Processes -- |g b). |t Total Synthesis of ABT-341 by One-Pot Sequence -- |t Conclusions -- |t CV of Yujiro Hayashi -- |t CV of Hayato Ishikawa -- |t References -- |g 10. |t Enantioselective Annulations with Chiral N-Mesityl N-Heterocyclic Carbenes / |r Jeffrey W. Bode -- |t Introduction -- |t Catalytic Generation of Chiral Enolate Equivalents -- |t Catalytic Generation of Homoenolate Equivalents -- |t Enantioselective Cascade Reactions Catalyzed by Chiral N-Heterocyclic Carbenes -- |t Catalytic Annulations via α, β-Unsaturated Acyl Azoliums -- |t Conclusions -- |t CV of Jeffrey Bode -- |t CV of Jessada Mahatthananchai -- |t References -- |g 11. |t Asymmetric Counteranion-Directed Catalysis (ACDC) / |r Benjamin List -- |t Concept -- |t Application of ACDC to Organocatalysis -- |t Application of ACDC to Transition Metal Catalysis -- |t Application of ACDC to Lewis Acid Catalysis -- |t CV of Manuel Mahlau -- |t CV of Prof. Dr. Benjamin List -- |t References -- |g 12. |t Enantioselective Organo-SOMO Catalysis: a Novel Activation Mode for Asymmetric Synthesis / |r Sebastian Rendler -- |t Background -- |t Objective -- |t Results -- |t CV of David W.C. MacMillan -- |t CV of Sebastian Rendler -- |t References -- |g 13. |t Enantioselective Passerini Reaction / |r Mei-Xiang Wang -- |t Introduction -- |t Background -- |t Results -- |t Conclusion and Perspective -- |t CV of Qian Wang -- |t CV of Jieping Zhu -- |t CV of Mei-Xiang Wang -- |t References -- |g 14. |t Rapid Enantiomeric Excess Determination / |r Oliver Trapp -- |t CV of Oliver Trapp -- |t References -- |g 15. |t Asymmetric Catalysis of Reversible Reactions / |r Lukas Hintermann -- |t Thermochemistry of Asymmetric Catalyses Close to the Equilibrium -- |t Kinetic Modeling of a Reversible Asymmetric Catalytic Reaction -- |t Case Study: a Reversible Asymmetric Organocatalytic Reaction -- |t Conclusions -- |t CV of Lukas Hintermann -- |t References -- |g 16. |t Exploiting Fluorine Conformational Effects in Organocatalyst Design: The Fluorine--Iminium Ion Gauche Effect / |r Ryan Gilmour -- |t CV of C. Sparr -- |t CV of L. Zimmer -- |t CV of R. Gilmour -- |t References -- |g 17. |t Dutch Resolution / |r Richard M. Kellogg -- |t CV of Richard M. Kellogg -- |t References -- |g 18. |t Construction of anti-Me-OH Vicinal Relationships in Polyketides / |r Martin E. Maier -- |t Introduction -- |t Marshall--Tamaru Reaction -- |t Conclusions -- |t CV of Vaidotas Navickas -- |t CV of Martin E. Maier -- |t References -- |g 19. |t Photoswitchable General Base Catalysts / |r Stefan Hecht -- |t Introduction and Background -- |t Strategy and Results -- |t Outlook -- |t CV of Philipp Viehmann -- |t CV of Stefan Hecht -- |t References -- |g 20. |t Asymmetric Halonium Addition to Olefins / |r Alexandria P. Brucks -- |t Introduction -- |t Intramolecular Lactonizations, Etherifications, and Aminations -- |t Polyene Cyclizations -- |t Intermolecular Additions to Alkenes -- |t Conclusion -- |t CV of Scott A. Snyder -- |t CV of Alexandria P. Brucks -- |t References -- |g 21. |t Catalytic Asymmetric Gosteli--Claisen Rearrangement (CAGC) / |r Martin Hiersemann -- |t CV of Julia Rehbein -- |t CV of Martin Hiersemann -- |t References -- |g 22. |t Biomimetic Total Synthesis of the Penifulvin Family / |r Johann Mulzer -- |t Introduction -- |t Penifulvin Family: Isolation and Biogenetic Origin -- |t Total Syntheses of Penifulvins A, B, and C -- |t Summary -- |t CV of Prof. Johann Mulzer -- |t CV of Tanja Gaich -- |t References -- |g 23. |t Catalyst-Controlled 1,3-Polyol Syntheses / |r Stefan F. Kirsch -- |t CV of Stefan F. Kirsch -- |t CV of Tobias Harschneck -- |t References -- |g 24. |t Enantioselective Carbonyl Allylation and Crotylation from the Alcohol Oxidation Level via C--C Bond Forming Transfer Hydrogenation / |r Michael J. Krische -- |t Introduction and Background -- |t Strategy -- |t Results -- |t CV of Michael Krische -- |t CV of Joseph Moran -- |t References -- |g 25. |t Stereoselective Synthesis with Hypervalent Iodine Reagents / |r Thomas Wirth -- |t CV of Umar Farid -- |t CV of Thomas Wirth -- |t References -- |g 26. |t Asymmetric Gold-Catalyzed Reactions / |r Antonio M. Echavarren -- |t Introduction -- |t Diphosphine-Gold Complexes in Enantioselective Catalysis -- |t Monophosphine-Gold Complexes in Enantioselective Catalysis -- |t CV of Nuria Huguet -- |t CV of Antonio M. Echavarren -- |t References -- |g 27. |t Asymmetric Catalysis in the Total Synthesis of Lipids and Polyketides / |r Adriaan J. Minnaard -- |t Background -- |t Tuberculostearic Acid: One Isolated Methyl Group -- |t Ant Pheromones: Vicinal Methyl Branches -- |t Deoxypropionates: 1,3-Methyl Arrays -- |t Membrane-Spanning Lipids: 1,4-Dimethyl Units -- |t Saturated Isoprenoids: 1,5-Methyl Arrays -- |t CV of Santiago Barroso -- |t CV of Adriaan J. Minnaard -- |t References -- |g 28. |t Evolving Role of Biocatalysis in Asymmetric Synthesis / |r Kurt Faber -- |t Background -- First- and Second-Generation Biotransformations -- |t Results--Third-Generation Biotransformations -- |g a). |t Asymmetric Bioreduction of C=C Bonds -- |g b). |t Asymmetric Transamination -- |t Conclusions and Future Perspectives -- |t CV of Melanie Hall -- |t CV of Wolfgang Kroutil -- |t CV of Kurt Faber -- |t References -- |g 29. |t Bifunctional Thiourea Catalysts / |r Tsubasa Inokuma -- |t Background -- |t Results -- |g a). |t Aminothiourea -- |g b). |t Hydroxythiourea -- |t CV of Yoshiji Takemoto -- |t CV of Tsubasa Inokuma -- |t References -- |g 30. |t Catalytic Asymmetric (4 + 3) Cycloadditions Using Allenamides / |r Richard P. Hsung -- |t Introduction and Background -- |t Strategy -- |t Results -- |t Conclusion -- |t CV of Yun-Fei Du -- |t CV of Richard P. Hsung -- |t References -- |g 31. |t Application of the Achmatowicz Rearrangement for the Synthesis of Oligosaccharides / |r George A. |
| 880 | 0 | 0 | |t O'Doherty -- |t Introduction -- |t De novo Approach to Carbohydrates -- |t Iterative Pd-Catalyzed Glycosylation and Bidirectional Postglycosylation -- |t Application to the Synthesis of the Anthrax Tetrasaccharide -- |t CV of Michael F. Cuccarese -- |t CV of George A. O'Doherty -- |t References -- |g 32. |t Asymmetric C--C Bond Formation Using Chiral Phosphoric Acid / |r Takahiko Akiyama -- |t Background -- |t Results -- |g a). |t Mannich and Related Reactions -- |g b). |t Cycloaddition Reactions -- |g c). |t Transfer Hydrogenation Reactions -- |g d). |t Friedel-Crafts Alkylation Reaction -- |g e). |t Desymmetrization reaction -- |t Conclusions and Future Perspectives -- |t CV of Takahiko Akiyama -- |t References -- |g 33. |t Asymmetric C--H Bond Functionalization / |r Jin-Quan Yu -- |t Background -- |t Results -- |g a). |t Diastereoselective C--H Functionalization -- |g b). |t Enantioselective C--H Functionalization -- |t Conclusions and Future Perspectives -- |t CV of Masayuki Wasa -- |t CV of Kelvin S.L. Chan -- |t CV of Jin-Quan Yu -- |t References -- |g 34. |t Asymmetric C--C Bond Formation Using Chiral Guanidine Catalysts / |r Masahiro Terada -- |t Background -- |t Catalyst Design and Results -- |g a). |t Design of Novel Axially Chiral Guanidine Base Catalysts -- |g b). |t Type I Axially Chiral Guanidine Catalysts (Nine-Membered Ring) -- |g c). |t Type II Axially Chiral Guanidine Catalysts (Seven-Membered Ring) |
| 880 | 0 | 0 | |6 505-01/(S |g Contents note continued: |t CV of Masahiro Terada -- |t References -- |g 35. |t Enantioselective Synthesis of Lactones via Rh-Catalyzed Ketone Hydroacylation / |r Vy M. Dong -- |t Background and Introduction -- |t Strategy and Results -- |t Conclusions and Future Directions -- |t CV of Vy M. Dong -- |t CV of Matthew M. Coulter -- |t References -- |g 36. |t Radical Haloalkylation / |r Armen Zakarian -- |t CV of Armen Zakarian -- |t References -- |g 37. |t Asymmetric Hydrovinylation of Alkenes / |r T.V. (Babu) RajanBabu -- |t Introduction -- |t New Protocols for the Heterodimerization of Ethylene/Propylene and Vinylarenes, 1,3-Dienes, and Norbornene -- |t Catalytic Asymmetric Hydrovinylation Reactions: Effects of Hemilabile Ligands -- |t All-Carbon Quaternary Centers via Catalytic Asymmetric HV -- |t Hydrovinylation (HV) of 1,3-Dienes and Asymmetric Variations -- |t Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes Using Co(II) Catalysis -- |t Scope and Applications of Hydrovinylation Reactions: Exocyclic Stereocontrol -- |t Stereoselective Route to either Steroid-C20(S) or -C20(R) Derivatives -- |t Asymmetric Hydrovinylation of Strained Alkenes -- |t Conclusions and Future Perspectives -- |t CV of T.V. (Babu) RajanBabu -- |t References -- |g 38. |t Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions / |r Tomislav Rovis -- |t Background -- |t Strategy -- |t Results -- |t Application to Other Reactions -- |t Conclusion and Future Perspectives -- |t CV of Tomislav Rovis -- |t CV of Kevin M. Oberg -- |t References -- |g 39. |t N-Heterocyclic Carbene-Catalyzed Aldol Desymmetrizations / |r Julien Dugal-Tessier -- |t Introduction -- |t Strategy and Results -- |t Application to the Syntheses of Bakkenolides I, J, and S -- |t Conclusion -- |t CV of Karl A. Scheidt -- |t CV of Eric M. Phillips -- |t CV of Julien Dugal-Tessier -- |t References -- |g 40. |t Strategies for the Asymmetric Total Synthesis of Natural Products: "Chiral Pool" versus Chiral Catalysts / |r Karl Gademann -- |t Introduction -- |t Catalytic Stereoselective Total Synthesis -- |t Natural Product Synthesis Starting from Chiral, Nonracemic Starting Materials -- |t Conclusion -- |t CV of Karl Gademann -- |t References -- |g 41. |t Dynamic Kinetic Asymmetric Transformations Involving Carbon--Carbon Bond Cleavage / |r Jeffrey S. Johnson -- |t Background -- |t Donor--Acceptor Cyclopropanes as DYKAT Substrates -- |t Lewis Acid Catalysis -- |t Palladium Catalysis -- |t Deracemization of Tertiary Propargyl-Allyl Alcohols via Rhodium-Catalyzed Sequential Rearrangement/Enantioselective Conjugate Addition -- |t Conclusion -- |t CV of Andrew Parsons -- |t CV of Jeffrey Johnson -- |t References -- |g 42. |t Iron-Catalyzed Allylic Substitutions / |r Bernd Plietker -- |t Allylic Substitutions Catalyzed by the Hieber-Anion [Fe(CO)3(NO)]- -- |t Allylic Substitutions Catalyzed by Fe2(CO)9 -- |t CV of Markus Jegelka -- |t CV of Bernd Plietker -- |t References -- |g 43. |t Asymmetric Conia-ene Carbocyclizations / |r Darren J. Dixon -- |t Introduction and Background: the Conia-ene Reaction -- |t Strategy: Organo/Metal Cooperative Catalysis -- |t Results -- |t CV of Filippo Sladojevich -- |t CV of Darren J. Dixon -- |t References -- |g 44. |t Tactics and Strategies in the Total Synthesis of Chlorosulfolipids / |r Erick M. Carreira -- |t Background -- |t Stereoselective Synthesis of vic-Dichloride Fragments -- |t Total Synthesis of Hexachlorosulfolipid -- |t Conclusions -- |t CV of Christian Nilewski -- |t CV of Erick M. Carreira -- |t References -- |g 45. |t Linear Free Energy Relationships (LFERs) in Asymmetric Catalysis / |r Matthew S. Sigman -- |t Introduction and Background -- |t Hammett Electronic Parameters and Their Application to (salen)Mn(III)-Catalyzed Asymmetric Epoxidation Reactions -- |t Relating Brønsted Acidity to Enantiomeric Ratio in an Asymmetric Hydrogen-Bond-Catalyzed Diels-Alder Reaction -- |t LFER Describing the Influence of Steric Bulk in a Nozaki--Hiyama--Kishi Asymmetric Allylation of Acetophenone -- |t Correlating Quadrupole Moment to Enantioselectivity in Cation-π-Mediated Asymmetric Polycyclization -- |t Simultaneously Correlating Hammett and Charton Parameters to Enantioselectivity in Two-Dimensional Free Energy Relationships -- |t Conclusions -- |t CV of Elizabeth Bess -- |t CV of Matt Sigman -- |t References -- |g 46. |t Asymmetric Diamination of Alkenes / |r Kilian Muniz -- |t Introduction and Background -- |t Strategy -- |t Results -- |t CV of Jose Souto -- |t CV of Kilian Muniz -- |t References -- |g 47. |t Enzymatic Asymmetric Synthesis of Tertiary Alcohols / |r Michael Richter -- |t Introduction -- |t YerE--a Unique ThDP-Dependent Enzyme -- |t Hydroxynitrile Lyases -- |t Conclusion -- |t CV of Michael Richter -- |t References -- |g 48. |t Oxidative Dearomatization and Organocatalytic Desymmetrization / |r Matthew J. Gaunt -- |t Introduction -- |t Desymmetrization of Cyclohexadienones -- |t One-Pot Oxidative Dearomatization and Catalytic Desymmetrization -- |t Oxo- and Aza-Michael Additions -- |t Further One-Pot Methods for Oxidative Dearomatization and Catalytic Desymmetrization -- |t Alkylative Dearomatization -- |t Summary -- |t CV of Matthew J. Gaunt -- |t CV of Alice E. Williamson -- |t References -- |g 49. |t Total Synthesis of All ( -- )-Agelastatin Alkaloids / |r Sunkyu Han -- |t Introduction -- |t Biosynthetically Inspired Plan for Total Synthesis -- |t Total Synthesis of the Agelastatin Alkaloids -- |t CV of Mohammad Movassaghi -- |t CV of Sunkyu Han -- |t References. |
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| 956 | |b Wiley Online Library: Complete oBooks | ||
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| 952 | f | f | |p Can circulate |a University of Colorado Boulder |b Online |c Online |d Online |e QD262 .A89 2012eb |h Library of Congress classification |i web |n 1 |