Polymeric chiral catalyst design and chiral polymer synthesis / edited by Shinichi Itsuno.
PVP is a highly safe polymer used in a wide variety of applications in medicine, pharmaceuticals, cosmetics, and industrial production. This book covers the chemistry, properties, and applications of PVP, including chiral polymer synthesis and its application to asymmetric catalysis. It discusses th...
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Language: | English |
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Hoboken, New Jersey :
John Wiley & Sons, Inc.,
[2011]
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Table of Contents:
- Frontmatter
- Color Plates
- An Overview of Polymer-Immobilized Chiral Catalysts and Synthetic Chiral Polymers / Shinichi Itsuno
- Polymer-Immobilized Chiral Organocatalyst / Naoki Haraguchi, Shinichi Itsuno
- Asymmetric Synthesis Using Polymer-Immobilized Proline Derivatives / Michelangelo Gruttadauria, Francesco Giacalone, Renato Noto
- Peptide-Catalyzed Asymmetric Synthesis / Kazuaki Kudo, Kengo Akagawa
- Continuous Flow System Using Polymer-Supported Chiral Catalysts / Santiago V Luis, Eduardo Garíca-Verdugo
- Chiral Synthesis on Polymer Support: A Combinatorial Approach / Deepak B Salunke, Chung-Ming Sun
- Synthesis and Application of Helical Polymers with Macromolecular Helicity Memory / Hiroki Iida, Eiji Yashima
- Poly(isocyanide)s, Poly(quinoxaline-2,3-diyl)s, and Related Helical Polymers Used as Chiral Polymer Catalysts in Asymmetric Synthesis / Yuuya Nagata, Michinori Suginome
- Chiral Biaryl Unit-Based Helical Polymers and their Application to Asymmetric Catalysis / Takeshi Maeda, Toshikazu Takata
- Immobilization of Multicomponent Asymmetric Catalysts (MACs) / Hiroaki Sasai, Shinobu Takizawa
- Optically Active Polymer and Dendrimer Synthesis and their Use in Asymmetric Catalysis / Qiao-Sheng Hu, Lin Pu
- Asymmetric Polymerizations of -Substituted Maleimides / Kenjiro Onimura, Tsutomu Oishi
- Synthesis of Hyperbranched Polymer Having Binaphthol Units via Oxidative Cross-Coupling Polymerization / Shigeki Habaue
- Optically Active Polyketones / Kyoko Nozaki
- Synthesis and Function of Chiral p-Conjugated Polymers from Phenylacetylenes / Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
- P-Stereogenic Oligomers, Polymers, and Related Cyclic Compounds / Yasuhiro Morisaki, Yoshiki Chujo.
- 14.2 ASYMMETRIC SYNTHESIS OF ISOTACTIC POLY(PROPYLENE-ALT-CO)
- 14.3 ASYMMETRIC SYNTHESIS OF ISOTACTIC SYNDIOTACTIC POLY(STYRENE-ALT-CO)
- 14.4 ASYMMETRIC TERPOLYMERS CONSISTING OF TWO KINDS OF OLEFINS AND CARBON MONOXIDE
- 14.5 ASYMMETRIC POLYMERIZATION OF OTHER OLEFINS WITH CO
- 14.6 CHEMICAL TRANSFORMATIONS OF OPTICALLY ACTIVE POLYKETONES
- 14.7 CONFORMATIONAL STUDIES ON THE OPTICALLY ACTIVE POLYKETONES
- 14.8 CONCLUSIONS
- REFERENCES
- 15 SYNTHESIS AND FUNCTION OF CHIRAL π-CONJUGATED POLYMERS FROM PHENYLACETYLENES
- 15.1 INTRODUCTION
- 15.2 HELIX-SENSE-SELECTIVE POLYMERIZATION (HSSP) OF SUBSTITUTED PHENYLACETYLENES AND FUNCTION OF THE RESULTING ONE-HANDED HELICAL POLY(PHENYLACETYLENE)S
- 15.2.1 Synthesis of Chiral π-Conjugated Polymers from Phenylacetylenes by Asymmetric-Induced Polymerization (AIP) and Helix-Sense-Selective Polymerization (HSSP) of Chiral and Achiral Phenylacetylenes
- 15.2.2 HSSP of Three Types of Monomers (RDHPA, RDAPA, and RDIPA, Scheme 15.4a)
- 15.2.3 Modified HSSP
- 15.2.4 Functions of One-Handed Helical Polyphenylacetylenes Prepared by HSSP
- 15.3 CHIRAL DESUBSTITUTION OF SIDE GROUPS IN MEMBRANE STATE
- 15.3.1 Polymer Reaction in Membrane State(RIM)
- 15.3.2 Reaction in One-Handed Helical Polymer Membranes: Synthesis of One-Handed Helical Polymers with no Chiral Side Groups and no Chiral Carbons
- 15.3.3 Reaction in Polystyrene Monolith: Synthesis of Chiral Porous Materials
- 15.4 SYNTHESIS OF CHIRAL POLYRADICALS
- 15.4.1 Molecular Design of Optically Active Helical Polyradicals
- 15.4.2 Copolymerization of the Monomers Possessing Radical and Chiral Moieties
- 15.4.3 Synthesis of Chiral Polyradicals via HSSP of Achiral Monomers
- REFERENCES
- 16 P-STEREOGENIC OLIGOMERS, POLYMERS, AND RELATED CYCLIC COMPOUNDS
- 16.1 INTRODUCTION.