Long term degradation of polyimide composites [microform] / Kaustubh A. Patekar and Hugh L. McManus.

"The durability of polymer matrix composites exposed to harsh environments is a major concern. Surface degradation and damage are observed in polyimide composites used in air at 125-300 C. It is believed that diffusion of oxygen into the material and oxidative chemical reactions are responsible...

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Bibliographic Details
Online Access: Click here to view full text online
Main Author: Patekar, Kaustubh A.
Corporate Author: Lewis Research Center
Other Authors: McManus, Hugh L. N., 1958-
Format: Government Document Microfilm Book
Language:English
Published: [Cleveland, Ohio] : Springfield, VA : National Aeronautics and Space Administration, Lewis Research Center ; National Technical Information Service, distributor, [1998]
Series:NASA contractor report ; NASA CR-208675.
Subjects:

MARC

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245 1 0 |a Long term degradation of polyimide composites  |h [microform] /  |c Kaustubh A. Patekar and Hugh L. McManus. 
260 |a [Cleveland, Ohio] :  |b National Aeronautics and Space Administration, Lewis Research Center ;  |a Springfield, VA :  |b National Technical Information Service, distributor,  |c [1998] 
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490 1 |a [NASA contractor report] ;  |v NASA/CR-1998-208675. 
504 |a Includes bibliographical references (page 9) 
520 |a "The durability of polymer matrix composites exposed to harsh environments is a major concern. Surface degradation and damage are observed in polyimide composites used in air at 125-300 C. It is believed that diffusion of oxygen into the material and oxidative chemical reactions are responsible. Previous work has characterized and modeled diffusion behavior, and thermogravimetric analyses (TGAS) have been carried out in nitrogen, air, and oxygen to provide quantitative information on thermal and oxidative reactions. However, the model developed using these data did not successfully extrapolate TGA data down to conditions seen in service. A test program that focuses on lower temperatures and makes use of isothermal tests was undertaken to achieve a better understanding of the degradation reactions under use conditions. A new, low-cost technique was developed to collect chemical degradation data for isothermal tests lasting over 200 hours in the temperature range 125-300 C. Results indicate complex behavior not captured by the previous model, including the presence of weight-adding reactions. Weight gain reactions dominated in the 125-225 C temperature range, while weight loss reactions dominated beyond 225 C. The data obtained from isothermal tests and earlier TGAs is used to develop an advanced model of the material behavior."--NASA Technical Reports Server web site. 
530 |a Available in microfiche and via the Internet. 
650 0 |a Polyimides.  |0 http://id.loc.gov/authorities/subjects/sh85104650. 
650 7 |a Polyimides.  |2 nasat. 
650 7 |a Polymer matrix composites.  |2 nasat. 
650 7 |a Thermogravimetry.  |2 nasat. 
650 7 |a Chemical properties.  |2 nasat. 
650 7 |a Degradation.  |2 nasat. 
650 7 |a Durability.  |2 nasat. 
650 7 |a Thermal stability.  |2 nasat. 
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