Structure-function relationships of second hyperpolarizabilities in two-dimensional molecules [electronic resource]

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Bibliographic Details
Online Access: Online Access
Corporate Author: Argonne National Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Argonne, Ill. : Oak Ridge, Tenn. : Argonne National Lab ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 1995.
Subjects:

MARC

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245 0 0 |a Structure-function relationships of second hyperpolarizabilities in two-dimensional molecules  |h [electronic resource] 
260 |a Argonne, Ill. :  |b Argonne National Lab ;  |a Oak Ridge, Tenn. :  |b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,   |c 1995. 
300 |a 10 p. 
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500 |a Published through the Information Bridge: DOE Scientific and Technical Information. 
500 |a 07/01/1995. 
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500 |a "CONF-950793--3" 
500 |a "DE95014233" 
500 |a 40. annual meeting of the Society of Photo-Optical Instrumentation Engineers, San Diego, CA (United States), 9-14 Jul 1995. 
500 |a Chen, L.X.; Mandal, B.K.; Bihari, B. 
500 |a USDOE, Washington, DC (United States);Department of Defense, Washington, DC (United States) 
520 3 |a The enhancement of the third order susceptibilities X{sup (3)} and second order molecular hyperpolarizabilities <γ> in a series of covalently stacked dimer and trimer macrocycles (SiPc and SiNc) was observed through the phase conjugated signals from DFWM measurements at both 1064 and 532 nm. The FWHM of the phase conjugated signals at 532 nm is much smaller than those at 1064 nm and those of the reference compound CS₂. The <γ> values at both wavelengths as a function of number of the monomer units (n) have an approximate n³ dependence, differing only in the scaling constant. The origin of such enhancement is discussed and compared to those in one-dimensional π-conjugated systems. 
536 |b W-31109-ENG-38. 
650 7 |a Phthalocyanines.  |2 local. 
650 7 |a Polarizability.  |2 local. 
650 7 |a Porphyrins.  |2 local. 
650 7 |a Silicon Compounds.  |2 local. 
650 7 |a Chlorophyll.  |2 local. 
650 7 |a Dimers.  |2 local. 
650 7 |a Absorption Spectra.  |2 local. 
650 7 |a Photochemistry.  |2 local. 
650 7 |a Electronic Structure.  |2 local. 
650 7 |a Chemistry.  |2 edbsc. 
710 2 |a Argonne National Laboratory.  |4 res. 
710 2 |a United States.  |b Department of Energy.  |b Office of Scientific and Technical Information.  |4 dst. 
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