|
|
|
|
| LEADER |
00000nam a22000003u 4500 |
| 001 |
b5968354 |
| 003 |
CoU |
| 005 |
20080206000000.0 |
| 006 |
m d f |
| 007 |
cr un |
| 008 |
100524e19920801dcu s| f1|||||eng|d |
| 035 |
|
|
|a (TOE)ost7037323
|
| 035 |
|
|
|a (TOE)7037323
|
| 040 |
|
|
|a TOE
|c TOE
|
| 049 |
|
|
|a GDWR
|
| 072 |
|
7 |
|a 37
|2 edbsc
|
| 086 |
0 |
|
|a E 1.99: conf-9208152--1
|
| 086 |
0 |
|
|a E 1.99:pnl-sa-21261
|
| 086 |
0 |
|
|a E 1.99: conf-9208152--1
|
| 245 |
0 |
0 |
|a Interactions between manganese oxides and multiple-ringed aromatic compounds
|h [electronic resource]
|
| 260 |
|
|
|a Washington, D.C. :
|b United States. Dept. of Defense ;
|a Oak Ridge, Tenn. :
|b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,
|c 1992.
|
| 300 |
|
|
|a Pages: (33 p) :
|b digital, PDF file.
|
| 336 |
|
|
|a text
|b txt
|2 rdacontent.
|
| 337 |
|
|
|a computer
|b c
|2 rdamedia.
|
| 338 |
|
|
|a online resource
|b cr
|2 rdacarrier.
|
| 500 |
|
|
|a Published through the Information Bridge: DOE Scientific and Technical Information.
|
| 500 |
|
|
|a 08/01/1992.
|
| 500 |
|
|
|a "pnl-sa-21261"
|
| 500 |
|
|
|a " conf-9208152--1"
|
| 500 |
|
|
|a "DE92041342"
|
| 500 |
|
|
|a ": 14-08-0001-G1723"
|
| 500 |
|
|
|a ISSS working group meeting, Edmonton (Canada), 10-16 Aug 1992.
|
| 500 |
|
|
|a Sims, R.C. . Dept. of Civil and Environm; Whelan, G.
|
| 520 |
3 |
|
|a Objective is to determine whether Mn reductive dissolution can oxidize multiple-ringed aromatics, such as PAHs, in an oxic environment Research indicated that certain PAHs (eg, dihydrodiols and diones that form free-radical intermediates) are susceptible to oxidation and polymerization. Over 14 days, 83, 76, 54, 70, and 20% of the Mn was reduced by 2,3-, 1,3-, and 1,4-naphthalenediol, quinizarin, and 1,4-naphthoquinone, respectively. 100, 100, and 65% of the first three PAHs were oxidized, respectively. Aromatics with diol functional groups were more easily oxidized than those with only dione groups. Relatively insoluble compounds like quinizarin can be oxidized; insoluble ''humic-like'' material precipitated, indicating a polymerization-humification process. Results suggest that electron transfer/organic release from the oxide surface is the rate-limiting step.
|
| 536 |
|
|
|b AC06-76RL01830.
|
| 650 |
|
7 |
|a Electron Transfer.
|2 local.
|
| 650 |
|
7 |
|a Kinetics.
|2 local.
|
| 650 |
|
7 |
|a Organic Compounds.
|2 local.
|
| 650 |
|
7 |
|a Waste Processing.
|2 local.
|
| 650 |
|
7 |
|a Separation Processes.
|2 local.
|
| 650 |
|
7 |
|a Precipitation.
|2 local.
|
| 650 |
|
7 |
|a Chemical Reaction Kinetics.
|2 local.
|
| 650 |
|
7 |
|a Transition Element Compounds.
|2 local.
|
| 650 |
|
7 |
|a Manganese Compounds.
|2 local.
|
| 650 |
|
7 |
|a Polycyclic Aromatic Hydrocarbons.
|2 local.
|
| 650 |
|
7 |
|a Processing.
|2 local.
|
| 650 |
|
7 |
|a Oxygen Compounds.
|2 local.
|
| 650 |
|
7 |
|a Management.
|2 local.
|
| 650 |
|
7 |
|a Ph Value.
|2 local.
|
| 650 |
|
7 |
|a Waste Management.
|2 local.
|
| 650 |
|
7 |
|a Aromatics.
|2 local.
|
| 650 |
|
7 |
|a Dissolution.
|2 local.
|
| 650 |
|
7 |
|a Chemical Reactions.
|2 local.
|
| 650 |
|
7 |
|a Oxides.
|2 local.
|
| 650 |
|
7 |
|a Polymerization.
|2 local.
|
| 650 |
|
7 |
|a Reduction.
|2 local.
|
| 650 |
|
7 |
|a Manganese Oxides.
|2 local.
|
| 650 |
|
7 |
|a Oxidation.
|2 local.
|
| 650 |
|
7 |
|a Hydrocarbons.
|2 local.
|
| 650 |
|
7 |
|a Reaction Kinetics.
|2 local.
|
| 650 |
|
7 |
|a Chalcogenides.
|2 local.
|
| 650 |
|
7 |
|a Inorganic, Organic, Physical And Analytical Chemistry.
|2 edbsc.
|
| 710 |
2 |
|
|a Pacific Northwest Laboratory.
|4 res.
|
| 710 |
1 |
|
|a United States.
|b Department of Defense.
|4 spn.
|
| 710 |
2 |
|
|a Geological Survey (U.S.).
|4 spn.
|
| 710 |
1 |
|
|a United States.
|b Department of Energy.
|4 spn.
|
| 710 |
2 |
|
|a Pacific Northwest National Laboratory (U.S.).
|4 res.
|
| 710 |
1 |
|
|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information.
|4 dst.
|
| 856 |
4 |
0 |
|u http://www.osti.gov/servlets/purl/7037323-X8mAEn/
|z Online Access
|
| 907 |
|
|
|a .b59683545
|b 03-06-23
|c 05-26-10
|
| 998 |
|
|
|a web
|b 05-26-10
|c f
|d m
|e p
|f eng
|g dcu
|h 0
|i 1
|
| 956 |
|
|
|a Information bridge
|
| 999 |
f |
f |
|i fb80afae-c0d2-57b1-9c85-e7f6ade11d7e
|s 1d053143-cf32-52c9-9d53-461ed209a090
|
| 952 |
f |
f |
|p Can circulate
|a University of Colorado Boulder
|b Online
|c Online
|d Online
|e E 1.99: conf-9208152--1
|h Superintendent of Documents classification
|i web
|n 1
|
