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|a (TOE)ost10184018
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|a (TOE)10184018
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|a TOE
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|a GDWR
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|a 37
|2 edbsc
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|a E 1.99: conf-920921--4
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|a E 1.99:anl/cp--76412
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|a E 1.99: conf-920921--4
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|a Kinetic studies of reactions of cobalt clusters with deuterium
|h [electronic resource]
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|a Washington, D.C. :
|b United States. Dept. of Energy ;
|a Oak Ridge, Tenn. :
|b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,
|c 1992.
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|a 9 p. :
|b digital, PDF file.
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|a text
|b txt
|2 rdacontent.
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|a computer
|b c
|2 rdamedia.
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|a online resource
|b cr
|2 rdacarrier.
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|a Published through the Information Bridge: DOE Scientific and Technical Information.
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|a 10/01/1992.
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|a "anl/cp--76412"
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|a " conf-920921--4"
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|a "DE93000514"
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|a 6. international symposium on small particles and inorganic clusters,Chicago, IL (United States),16-22 Sep 1992.
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|a Parks, E.K.; Riley, S.J.; Zhu, L.; Ho, J.
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|a The kinetics of chemical reactions of cobalt clusters Co{sub n} with deuterium are described. Absolute rate constants have been measured in the cluster range n = 7--68 at 293 K. The rate constants are found to be a strong function of cluster size, varying by up to three orders of magnitude. This size , dependence is most prominent in the n = 7--25 size range: CO₁₅ is the most reactive cluster, and CO₇₋₉ and CO₁₉₋₋₂₀ are particularly unreactive. Abrupt changes in the rate constants from one cluster size to the next are observed. For the clusters above n = 25, the rate constants show several less prominent maxima and minima superimposed on a slow, nearly monotonic increase with cluster size.
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|b W-31109-ENG-38.
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|a Chemical Reaction Kinetics.
|2 local.
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|a Temperature Range 0273-0400 K.
|2 local.
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|a Deuterium.
|2 local.
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|a Chemical Reactions.
|2 local.
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|a Atomic Clusters.
|2 local.
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|a Cobalt.
|2 local.
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|a Molecule-molecule Collisions.
|2 local.
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|a Inorganic, Organic, Physical And Analytical Chemistry.
|2 edbsc.
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|a Argonne National Laboratory.
|4 res.
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|a United States.
|b Department of Energy.
|4 spn.
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|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information.
|4 dst.
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|u http://www.osti.gov/servlets/purl/10184018-IlI2dg/
|z Online Access
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907 |
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|a .b59710615
|b 03-06-23
|c 05-26-10
|
998 |
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|a web
|b 05-26-10
|c f
|d m
|e p
|f eng
|g dcu
|h 0
|i 1
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|a Information bridge
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|i a1c544cf-a1ce-52dc-81eb-87bdf31fe15a
|s 71c86d8c-c3ec-5ce6-8e2d-6d8b3eb91b64
|
952 |
f |
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|p Can circulate
|a University of Colorado Boulder
|b Online
|c Online
|d Online
|e E 1.99: conf-920921--4
|h Superintendent of Documents classification
|i web
|n 1
|