Kinetic studies of reactions of cobalt clusters with deuterium [electronic resource]

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Bibliographic Details
Online Access: Online Access
Corporate Author: Argonne National Laboratory (Researcher)
Format: Government Document Electronic eBook
Language:English
Published: Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 1992.
Subjects:

MARC

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245 0 0 |a Kinetic studies of reactions of cobalt clusters with deuterium  |h [electronic resource] 
260 |a Washington, D.C. :  |b United States. Dept. of Energy ;  |a Oak Ridge, Tenn. :  |b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,  |c 1992. 
300 |a 9 p. :  |b digital, PDF file. 
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500 |a 10/01/1992. 
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500 |a 6. international symposium on small particles and inorganic clusters,Chicago, IL (United States),16-22 Sep 1992. 
500 |a Parks, E.K.; Riley, S.J.; Zhu, L.; Ho, J. 
520 3 |a The kinetics of chemical reactions of cobalt clusters Co{sub n} with deuterium are described. Absolute rate constants have been measured in the cluster range n = 7--68 at 293 K. The rate constants are found to be a strong function of cluster size, varying by up to three orders of magnitude. This size , dependence is most prominent in the n = 7--25 size range: CO₁₅ is the most reactive cluster, and CO₇₋₉ and CO₁₉₋₋₂₀ are particularly unreactive. Abrupt changes in the rate constants from one cluster size to the next are observed. For the clusters above n = 25, the rate constants show several less prominent maxima and minima superimposed on a slow, nearly monotonic increase with cluster size. 
536 |b W-31109-ENG-38. 
650 7 |a Chemical Reaction Kinetics.  |2 local. 
650 7 |a Temperature Range 0273-0400 K.  |2 local. 
650 7 |a Deuterium.  |2 local. 
650 7 |a Chemical Reactions.  |2 local. 
650 7 |a Atomic Clusters.  |2 local. 
650 7 |a Cobalt.  |2 local. 
650 7 |a Molecule-molecule Collisions.  |2 local. 
650 7 |a Inorganic, Organic, Physical And Analytical Chemistry.  |2 edbsc. 
710 2 |a Argonne National Laboratory.  |4 res. 
710 1 |a United States.  |b Department of Energy.  |4 spn. 
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