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100524e19920701dcu s| f1|||||eng|d |
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|a (TOE)ost10153022
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|a (TOE)10153022
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|a TOE
|c TOE
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|a GDWR
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|a 37
|2 edbsc
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| 086 |
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|a E 1.99: conf-9105162--1
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| 086 |
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|a E 1.99:anl/cp--72683
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| 086 |
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|a E 1.99: conf-9206180--2
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| 086 |
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|a E 1.99: conf-9105162--1
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| 245 |
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|a Flash photolysis-shock tube studies of biomolecular reactions
|h [electronic resource]
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| 260 |
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|a Washington, D.C. :
|b United States. Dept. of Energy ;
|a Oak Ridge, Tenn. :
|b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,
|c 1992.
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| 300 |
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|a 5 p. :
|b digital, PDF file.
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| 336 |
|
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|a text
|b txt
|2 rdacontent.
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| 337 |
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|a computer
|b c
|2 rdamedia.
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| 338 |
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|a online resource
|b cr
|2 rdacarrier.
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| 500 |
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|a Published through the Information Bridge: DOE Scientific and Technical Information.
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| 500 |
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|a 07/01/1992.
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| 500 |
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|a "anl/cp--72683"
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| 500 |
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|a " conf-9206180--2"
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| 500 |
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|a " conf-9105162--1"
|
| 500 |
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|a "DE92015190"
|
| 500 |
|
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|a 14. combustion research meeting,Tahoe City, CA (United States); Lake Geneva, WI (United States),14-17 Jun 1992; 28-31 May 1991.
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| 500 |
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|a Michael, J.V.
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| 520 |
3 |
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|a Three experiments were completed during the past year. The rate constant for the reaction O + CH₃Cl → OH + CH₂Cl at 556 to 1485 K, was determined to be k₁ = 2.57 × 10⁻¹¹T{sup 0.31}exp(-5633 K/T)cm³/molecule·s. The rate constant for the reaction N + NO → N₂ + O at 1251-3152 K, was determined to be k₃ = (3.7±0.9)×10⁻¹¹cm³/molecule·s. The pyrolysis of CH₃Cl can be represented by the Arrhenius equation, k₅ = 9.6×10⁹exp(-27449 K/T)s₋₁. The pyrolysis photolysis-shock tube technique was used to study the O + CH₃ reaction at 1609 to 1972 K; fits to O-atom profiles gives the T-independent rate constant k₆ = (1.4±0.3)×10⁻¹°cm³/molecule·s. 1 fig., 14 refs. (DLC)
|
| 536 |
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|b W-31109-ENG-38.
|
| 650 |
|
7 |
|a Chloroform.
|2 local.
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| 650 |
|
7 |
|a Atoms.
|2 local.
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| 650 |
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7 |
|a Nitrogen.
|2 local.
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| 650 |
|
7 |
|a Shock Tubes.
|2 local.
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| 650 |
|
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|a Temperature Range 0400-1000 K.
|2 local.
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| 650 |
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7 |
|a Methyl Radicals.
|2 local.
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| 650 |
|
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|a Chemical Reaction Kinetics.
|2 local.
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| 650 |
|
7 |
|a Temperature Range 1000-4000 K.
|2 local.
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| 650 |
|
7 |
|a Chemical Reactions.
|2 local.
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| 650 |
|
7 |
|a Photolysis.
|2 local.
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| 650 |
|
7 |
|a Pyrolysis.
|2 local.
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| 650 |
|
7 |
|a Oxygen.
|2 local.
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| 650 |
|
7 |
|a Nitric Oxide.
|2 local.
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| 650 |
|
7 |
|a Atom-molecule Collisions.
|2 local.
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| 650 |
|
7 |
|a Inorganic, Organic, Physical And Analytical Chemistry.
|2 edbsc.
|
| 710 |
2 |
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|a Argonne National Laboratory.
|4 res.
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| 710 |
1 |
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|a United States.
|b Department of Energy.
|4 spn.
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| 710 |
1 |
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|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information.
|4 dst.
|
| 856 |
4 |
0 |
|u http://www.osti.gov/servlets/purl/10153022-JBSlnO/
|z Online Access
|
| 907 |
|
|
|a .b59742446
|b 03-06-23
|c 05-26-10
|
| 998 |
|
|
|a web
|b 05-26-10
|c f
|d m
|e p
|f eng
|g dcu
|h 0
|i 1
|
| 956 |
|
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|a Information bridge
|
| 999 |
f |
f |
|i ba9cf2ce-5c10-503a-a60a-9f7d2b1c27f4
|s dabd824d-4cef-5ea4-843d-26f06a2286e5
|
| 952 |
f |
f |
|p Can circulate
|a University of Colorado Boulder
|b Online
|c Online
|d Online
|e E 1.99: conf-9105162--1
|h Superintendent of Documents classification
|i web
|n 1
|
