|
|
|
|
| LEADER |
00000nam a22000003u 4500 |
| 001 |
b6014165 |
| 003 |
CoU |
| 005 |
20080610000000.0 |
| 006 |
m d f |
| 007 |
cr un |
| 008 |
100527e19800101nyu st f0|||||eng|d |
| 035 |
|
|
|a (TOE)ost6927680
|
| 035 |
|
|
|a (TOE)6927680
|
| 040 |
|
|
|a TOE
|c TOE
|
| 049 |
|
|
|a GDWR
|
| 072 |
|
7 |
|a 38
|2 edbsc
|
| 086 |
0 |
|
|a E 1.99:rfp-3108
|
| 086 |
0 |
|
|a E 1.99:rfp-3108
|
| 245 |
0 |
0 |
|a Effect of vacuum heat treatment on plutonium oxide surfaces as studied by XPS and AES
|h [electronic resource]
|
| 260 |
|
|
|a New York, N.Y. :
|b Rockefeller University ;
|a Oak Ridge, Tenn. :
|b distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy,
|c 1980.
|
| 300 |
|
|
|a Pages: 10 :
|b digital, PDF file.
|
| 336 |
|
|
|a text
|b txt
|2 rdacontent.
|
| 337 |
|
|
|a computer
|b c
|2 rdamedia.
|
| 338 |
|
|
|a online resource
|b cr
|2 rdacarrier.
|
| 500 |
|
|
|a Published through the Information Bridge: DOE Scientific and Technical Information.
|
| 500 |
|
|
|a 01/01/1980.
|
| 500 |
|
|
|a "rfp-3108"
|
| 500 |
|
|
|a Larson, D.T.
|
| 500 |
|
|
|a Rockwell International Corp., Canoga Park, CA (USA). Energy Systems Group.
|
| 520 |
3 |
|
|a The effect of heating (150 to 500°C) in vacuum a plutonium substrate with a plutonium oxide surface film was studied utilizing X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES). When plutonium metal with a surface oxide film is vacuum heat treated, the oxide is reduced by reaction of the substrate metal with the oxide. The reactions occurring were examined by monitoring the binding energies of the Pu(4f₇₂), O(1s), and C(1s) XPS peaks and observing the C(KLL) Auger electron peak structure. These results were compared with the x-ray diffraction data of Terada et al. (J. Nucl. Mater. 30: 340(1969). The XPS and AES data show that at higher reaction temperatures (400 to 500°C) the surface compound formed is not PuO as indicated by Terada et al., but is instead a plutonium oxycarbide (Pu(C,O)) compound. The Pu(4f₇₂) binding energies for PuO₂, PuO₁ ₅₂ (..cap alpha..-Pu₂O₃), Pu(C,O), and Pu metal are 426.1, 424.4, 423.6, and 422.2 eV, respectively.
|
| 536 |
|
|
|b AC04-76DP03533.
|
| 650 |
|
7 |
|a Binding Energy.
|2 local.
|
| 650 |
|
7 |
|a X-ray Diffraction.
|2 local.
|
| 650 |
|
7 |
|a Scattering.
|2 local.
|
| 650 |
|
7 |
|a Films.
|2 local.
|
| 650 |
|
7 |
|a Oxygen Compounds.
|2 local.
|
| 650 |
|
7 |
|a Actinide Compounds.
|2 local.
|
| 650 |
|
7 |
|a Carbon Compounds.
|2 local.
|
| 650 |
|
7 |
|a Plutonium Oxides.
|2 local.
|
| 650 |
|
7 |
|a Plutonium Compounds.
|2 local.
|
| 650 |
|
7 |
|a Elements.
|2 local.
|
| 650 |
|
7 |
|a Oxygen.
|2 local.
|
| 650 |
|
7 |
|a Electron Spectroscopy.
|2 local.
|
| 650 |
|
7 |
|a Carbon.
|2 local.
|
| 650 |
|
7 |
|a Spectroscopy.
|2 local.
|
| 650 |
|
7 |
|a Actinides.
|2 local.
|
| 650 |
|
7 |
|a Diffraction.
|2 local.
|
| 650 |
|
7 |
|a Nonmetals.
|2 local.
|
| 650 |
|
7 |
|a Transuranium Compounds.
|2 local.
|
| 650 |
|
7 |
|a Metals.
|2 local.
|
| 650 |
|
7 |
|a Photoelectron Spectroscopy.
|2 local.
|
| 650 |
|
7 |
|a High Temperature.
|2 local.
|
| 650 |
|
7 |
|a Oxycarbides.
|2 local.
|
| 650 |
|
7 |
|a Coherent Scattering.
|2 local.
|
| 650 |
|
7 |
|a Heat Treatments.
|2 local.
|
| 650 |
|
7 |
|a Auger Electron Spectroscopy.
|2 local.
|
| 650 |
|
7 |
|a Energy.
|2 local.
|
| 650 |
|
7 |
|a Transuranium Elements.
|2 local.
|
| 650 |
|
7 |
|a Substrates.
|2 local.
|
| 650 |
|
7 |
|a Oxides.
|2 local.
|
| 650 |
|
7 |
|a Plutonium.
|2 local.
|
| 650 |
|
7 |
|a Chalcogenides.
|2 local.
|
| 650 |
|
7 |
|a Radiation Chemistry, Radiochemistry, And Nuclear Chemistry.
|2 edbsc.
|
| 710 |
2 |
|
|a Rockefeller University.
|4 res.
|
| 710 |
1 |
|
|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information.
|4 dst.
|
| 856 |
4 |
0 |
|u http://www.osti.gov/servlets/purl/6927680-lKwPNA/
|z Online Access
|
| 907 |
|
|
|a .b60141657
|b 03-06-23
|c 05-30-10
|
| 998 |
|
|
|a web
|b 05-30-10
|c f
|d m
|e p
|f eng
|g nyu
|h 0
|i 1
|
| 956 |
|
|
|a Information bridge
|
| 999 |
f |
f |
|i f84bd3ec-f0f2-51bf-9661-f7c68396b625
|s 6ab5f313-c421-51a7-b9df-1ceccc098122
|
| 952 |
f |
f |
|p Can circulate
|a University of Colorado Boulder
|b Online
|c Online
|d Online
|e E 1.99:rfp-3108
|h Superintendent of Documents classification
|i web
|n 1
|
