ESR Spectroscopy in Polymer Research / by B. Rånby, J.F. Rabek.

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Bibliographic Details
Online Access: Full Text (via Springer)
Main Author: Rånby, B.
Other Authors: Rabek, J. F.
Format: eBook
Language:English
Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 1977.
Series:Polymers, properties and applications ; 1.
Subjects:

MARC

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245 1 0 |a ESR Spectroscopy in Polymer Research /  |c by B. Rånby, J.F. Rabek. 
260 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg,  |c 1977. 
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490 1 |a Polymers Properties and Applications, 0171-7901 ;  |v 1. 
505 0 |a 1. Generation of Free Radicals -- 1.1. Free Radicals, Biradicals, and Radical Ions -- 1.2. Basic Properties of Free Radicals -- 1.3. Free Radical Reactions -- 1.4. Interaction of Electromagnetic Radiation with Matter -- 1.5. Interaction of Charged Particles with Matter -- 1.6. Physical Sources of Free Radicals -- 1.7. Chemical Sources for the Production of Free Radicals -- 2. Principles of ESR Spectroscopy -- 2.1. Introduction -- 2.2. Interaction Between the Electron Spin and Internal Magnetic Field -- 2.3. Spin Relaxation -- 2.4. The Shape of ESR Resonance Lines -- 2.5. g-Value -- 2.6. Interaction Between the Electron and the Nuclear Spins -- 3. Experimental Instrumentation of Electron Spin Resonance -- 3.1. ESR Spectrometers -- 3.2. Field Sweep Calibration -- 3.3. Measurements of Spin Concentration -- 3.4. Measurements of ESR Spectra at Different Temperatures -- 3.5. Computer Application into ESR Spectroscopy -- 3.6. Preparation of Samples for ESR Experiments -- 3.7. Special Techniques for ESR Spectroscopy -- 4. ESR Study of Polymerization Processes -- 4.1. Homogeneous Chain-growth Polymerization -- 4.2. Ionizing Polymerization -- 4.3. Photopolymerization -- 4.4. Thermal Polymerization -- 4.5. Polymerization Initiated by Mechano-radicals -- 4.6. Polymerization Initiated by Various Free Radical Initiation Systems -- 4.7. Anionic Polymerization -- 4.8. Cationic Polymerization -- 4.9. Heterogenous Chain-Growth Polymerization -- 5. ESR Study of Degradation Processes in Polymers -- 5.1. Radiation and Photo-Degradation of Polymers -- 5.2. Free Radicals Formed in Glow Discharge of Polymers -- 5.3. Anionic Degradation of Vinylaromatic Polymers -- 5.4. Reaction of Polymers with Hydroxy Radicals -- 6. ESR Study of Polymers in Reactive Gases -- 6.1. Molecular Oxygen -- 6.2. Singlet Oxygen -- 6.3. Atomic Oxygen -- 6.4. Atomic Hydrogen -- 6.5. Atomic Nitrogen -- 6.6. Noble Gases -- 6.7. Other Gases -- 7. ESR Studies of the Oxidation of Polymers -- 7.1. Radiation-Induced Oxidation of Polymers -- 7.2. Polyethylene -- 7.3. Polypropylene -- 7.4. Poly(tetrafluoroethylene) -- 7.5. ESR Studies of Antioxidants -- 8. ESR Studies of Molecular Fracture in Polymers -- 8.1. Introduction -- 8.2. Generation of Submicrocracks -- 8.3. Generation of Free Radicals in Mechanically Deformed Polyethylene -- 8.4. ESR Study of Free Radicals Formed During Fracture in Rubber -- 8.5. ESR Study of Fatigue Processes in Polymers -- 8.6. ESR Study of Free Radicals Formed During Grinding and Machining of Polymers -- 8.7. Anomalous Behavior of Free Radicals Obtained by Sawing Technique -- 8.8. Mechanical Degradation of Polymers in Frozen Solution Matrix -- 9. ESR Studies of Graft Copolymerization -- 9.1. Graft Copolymerization of Polyethylene -- 9.2. Cellulose Graft Copolymers -- 9.3. Miscellaneous Problems -- 10. ESR Studies of Crosslinking -- 10.1. ESR Study of Enhanced Crosslinking of Polymers -- 10.2. ESR Study of Free Radicals Observed During the Curing of Unsaturated Polyester Resins -- 10.3. ESR Study of the Vulcanization of Rubber -- 10.4. ESR Spectra of Light-Irradiated Poly(vinyl cinnamate) -- 11. Application of Stable Free Radicals in Polymer Research -- 11.1. Nitroxide Radicals -- 11.2. Spin-Probe Technique -- 11.3. Spin-Trapping Technique -- 11.4. Spin-Labeling Technique -- 12. ESR Spectroscopy of Stable Polymer Radicals and their Low Molecular Analogues -- 12.1. Poly(triphenylmethyl) Radicals -- 12.2. Poly(?,??-diphenyl-p-xylene) Radicals -- 12.3. Polyphenoxy Radicals -- 12.4. Poly(triphenylhydrazyl) Radicals -- 12.5. Polymers Containing Stable Free Radicals of the Nitroxide Type -- 12.6. Poly(pyridinyl) Radicals -- 12.7. Poly(verdazyl) Radicals -- 12.8. Polymers Containing Stable Free Radicals of the Tetrazine Type -- 12.9. Polyradical Anions -- 12.10. ESR Study of Donor-Acceptor Polymer Complexes -- 12.11. Organic Polymeric Semiconductors -- 12.12. Free Radicals Formed by Pyrolysis of Polymers -- 12.13. Free Radicals in Carbon Black -- 13. ESR Study of Ion-Exchange Resins -- References. 
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