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The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide [electronic resource] / by Gisela Henrici-Olivé, Salvador Olivé.

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During the oil embargo, in the winter 1973174, parts of Western Europe present­ ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high­ ways, no crowds at ski resorts and other weekend entertainment places, no gaso­ line at the pumps. Living and teaching then in that part of t...

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Bibliographic Details
Online Access: Full Text (via Springer)
Main Author: Henrici-Olivé, G. (Gisela), 1925-
Other Authors: Olivé, S. (Salvador), 1922-
Format: Electronic eBook
Language:English
Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 1984.
Subjects:
Chemistry.
Chemistry, Inorganic.
Surfaces (Physics)
Table of Contents:
  • 1 Introduction
  • 1.1 References
  • 2 Transition Metal-Hydrogen Interactions
  • 2.1 Reaction of Hydrogen with Transition Metal Complexes and Surfaces
  • 2.2 Metal-Hydrogen Bond Energy
  • 2.3 Different Types of Metal-Hydrogen Bonding and the M-H Bond Length
  • 2.4 Polarity of the M-H Bond
  • 2.5 Mobility of Hydrogen Ligands
  • 2.6 Conclusion
  • 2.7 References
  • 3 Transition Metal-Carbon Monoxide Interactions
  • 3.1 The CO Molecule
  • 3.2 Coordination Chemistry of CO in Molecular Complexes and Clusters
  • 3.3 Molecular Carbon Monoxide on Metal Surfaces
  • 3.4 CO Dissociation on Metal Surfaces
  • 3.5 Conclusion
  • 3.6 References
  • 4 Non-Catalytic Interaction of CO with H2
  • 4.1 On Metal Surfaces
  • 4.2 CO/H2 Interaction in Transition Metal Complexes
  • 4.3 Conclusions
  • 4.4 References
  • 5 Key Reactions in Catalysis
  • 5.1 Oxidative Addition
  • 5.2 Reductive Elimination
  • 5.3 Migratory Insertion Reactions
  • 5.4 Hydrogen Eliminiation Reactions
  • 5.5 Ligand Influences
  • 5.6 Conclusion
  • 5.7 References
  • 6 Catalysts and Supports
  • 6.1 Molecular Complexes and Metal Surfaces
  • Analogies and Differences
  • 6.2 Supported Metal Catalysts
  • 6.3 Conclusions
  • 6.4 References
  • 7 Methanation
  • 7.1 Carbide Mechanism
  • 7.2 CO Insertion Mechanism
  • 7.3 Inverse H/D Isotope Effects
  • 7.4 Conclusion
  • 7.5 References
  • 8 Methanol from CO + H2
  • 8.1 Nondissociative Incorporation of CO
  • 8.2 Homogeneous Methanol Formation
  • 8.3 Methanol Synthesis with Supported Noble Metal Catalysts
  • 8.4 Synergism in the Cu/ZnO Catalyst
  • 8.5 Conclusions
  • 8.6 References
  • 9 Fischer-Tropsch Synthesis
  • 9.1 Early Developments and Present State of Commercial Fischer-Tropsch Synthesis
  • 9.2 The Products of the FT Synthesis
  • 9.3 Distribution of Molecular Weights
  • 9.4 Kinetics and Thermodynamics of the FT Reaction
  • 9.5 Reaction Mechanism
  • 9.6 Influence of the Dispersity of Metal Centers
  • 9.7 Influence of the Temperature and Pressure
  • 9.8 The Role of Alkali Promoters
  • 9.9 Product Selectivity
  • 9.10 Conclusion
  • 9.11 References
  • 10 Homogeneous CO Hydrogenation
  • 10.1 Hydroformylation of Olefins (Oxo Reaction)
  • 10.2 Hydroformylation of Formaldehyde
  • 10.3 Polyalcohols from CO + H2, and Related Homogeneous Syntheses
  • 10.4 Conclusion
  • 10.5 References
  • 11 Methanol as Raw Material
  • 11.1 Carbonylation of Methanol (Acetic Acid Synthesis).
  • 11.2 Methanol Homologation
  • 11.3 Hydrocarbons from Methanol Dehydration and Condensation
  • 11.4 Conclusion
  • 11.5 References
  • 12 Attempt of a Unified View
  • 12.1 References
  • 13 Subject Index.

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