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b8094733 |
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CoU |
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20150413222615.7 |
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m o d f |
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cr ||||||||||| |
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150804e19820601||| ot f0|||||eng|d |
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|a (TOE)ost5195650
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|a (TOE)5195650
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|a TOE
|c TOE
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|a GDWR
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|a 37
|2 edbsc
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|a 11
|2 edbsc
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| 086 |
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|a E 1.99:dp-1632
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|a E 1.99:dp-1632
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| 088 |
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|a dp-1632
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| 245 |
0 |
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|a Determination of free acid by standard addition method in potassium thiocyanate
|h [electronic resource]
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| 260 |
|
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|a Aiken, S.C :
|b Savannah River Laboratory ;
|a Oak Ridge, Tenn. :
|b distributed by the Office of Scientific and Technical Information, U.S. Department of Energy,
|c 1982.
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| 300 |
|
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|a Pages: 52 :
|b digital, PDF file.
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| 336 |
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|a text
|b txt
|2 rdacontent.
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| 337 |
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|a computer
|b c
|2 rdamedia.
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| 338 |
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|a online resource
|b cr
|2 rdacarrier.
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| 500 |
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|a Published through SciTech Connect.
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| 500 |
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|a 06/01/1982.
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| 500 |
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|a "dp-1632"
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| 500 |
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|a "DE82017563"
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| 500 |
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|a Baumann, E W.
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| 520 |
3 |
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|a The free acid content of solutions containing hydrolyzable ions has been determined potentiometrically by a standard addition method. Two increments of acid are added to the sample in 1M potassium thiocyanate solution. The sample concentration is calculated by solution of three simultaneous Nernst equations. The method has been demonstrated for solutions containing Al/sup 3 +/, Cr/sup 3 +/, Fe/sup 3 +/, Hg/sup 2 +/, Ni/sup 2 +/, Th/sup 4 +/, or UO/sub 2//sup 2 +/ with a metal-to-acid ratio of < 2.5. The method is suitable for determination of 10 ..mu..moles acid in 10 mL total volume. The accuracy can be judged from the agreement of the Nernst slopes found in the presence and absence of hydrolyzable ions. The relative standard deviation is < 2.5%. The report includes a survey of experiments with thermometric, pH, and Gran plot titrations in a variety of complexants, from which the method was evolved. Also included is a literature survey of sixty references, a discussion of the basic measurements, and a complete analytical procedure.
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| 536 |
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|b AC09-76SR00001.
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| 650 |
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7 |
|a Nitric Acid.
|2 local.
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| 650 |
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7 |
|a Potentiometry.
|2 local.
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| 650 |
|
7 |
|a Accuracy.
|2 local.
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| 650 |
|
7 |
|a Aluminium Nitrates.
|2 local.
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| 650 |
|
7 |
|a Chromium Nitrates.
|2 local.
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| 650 |
|
7 |
|a Experimental Data.
|2 local.
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| 650 |
|
7 |
|a Hydrolysis.
|2 local.
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| 650 |
|
7 |
|a Interfering Elements.
|2 local.
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| 650 |
|
7 |
|a Iron Nitrates.
|2 local.
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| 650 |
|
7 |
|a Mercury Nitrates.
|2 local.
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| 650 |
|
7 |
|a Nickel Nitrates.
|2 local.
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| 650 |
|
7 |
|a Potassium Compounds.
|2 local.
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| 650 |
|
7 |
|a Quantitative Chemical Analysis.
|2 local.
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| 650 |
|
7 |
|a Reviews.
|2 local.
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| 650 |
|
7 |
|a Thiocyanates.
|2 local.
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| 650 |
|
7 |
|a Thorium Nitrates.
|2 local.
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| 650 |
|
7 |
|a Uranyl Nitrates.
|2 local.
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| 650 |
|
7 |
|a Actinide Compounds.
|2 local.
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| 650 |
|
7 |
|a Alkali Metal Compounds.
|2 local.
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| 650 |
|
7 |
|a Aluminium Compounds.
|2 local.
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| 650 |
|
7 |
|a Antithyroid Drugs.
|2 local.
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| 650 |
|
7 |
|a Carbonic Acid Derivatives.
|2 local.
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| 650 |
|
7 |
|a Chemical Analysis.
|2 local.
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| 650 |
|
7 |
|a Chemical Reactions.
|2 local.
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| 650 |
|
7 |
|a Chromium Compounds.
|2 local.
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| 650 |
|
7 |
|a Data.
|2 local.
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| 650 |
|
7 |
|a Decomposition.
|2 local.
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| 650 |
|
7 |
|a Document Types.
|2 local.
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| 650 |
|
7 |
|a Drugs.
|2 local.
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| 650 |
|
7 |
|a Hormone Antagonists.
|2 local.
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| 650 |
|
7 |
|a Hydrogen Compounds.
|2 local.
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| 650 |
|
7 |
|a Information.
|2 local.
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| 650 |
|
7 |
|a Inorganic Acids.
|2 local.
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| 650 |
|
7 |
|a Iron Compounds.
|2 local.
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| 650 |
|
7 |
|a Lysis.
|2 local.
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| 650 |
|
7 |
|a Mercury Compounds.
|2 local.
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| 650 |
|
7 |
|a Nickel Compounds.
|2 local.
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| 650 |
|
7 |
|a Nitrates.
|2 local.
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| 650 |
|
7 |
|a Nitrogen Compounds.
|2 local.
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| 650 |
|
7 |
|a Numerical Data.
|2 local.
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| 650 |
|
7 |
|a Organic Compounds.
|2 local.
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| 650 |
|
7 |
|a Organic Sulfur Compounds.
|2 local.
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| 650 |
|
7 |
|a Oxygen Compounds.
|2 local.
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| 650 |
|
7 |
|a Solvolysis.
|2 local.
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| 650 |
|
7 |
|a Thorium Compounds.
|2 local.
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| 650 |
|
7 |
|a Titration.
|2 local.
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| 650 |
|
7 |
|a Transition Element Compounds.
|2 local.
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| 650 |
|
7 |
|a Uranium Compounds.
|2 local.
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| 650 |
|
7 |
|a Uranyl Compounds.
|2 local.
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| 650 |
|
7 |
|a Inorganic, Organic, Physical And Analytical Chemistry.
|2 edbsc.
|
| 650 |
|
7 |
|a Nuclear Fuel Cycle And Fuel Materials.
|2 edbsc.
|
| 700 |
1 |
|
|a Baumann, E W
|4 aut.
|
| 710 |
2 |
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|a Savannah River Laboratory.
|4 res.
|
| 710 |
1 |
|
|a United States.
|b Department of Energy.
|b Office of Scientific and Technical Information.
|4 dst.
|
| 856 |
4 |
0 |
|u http://www.osti.gov/servlets/purl/5195650/
|z Online Access
|
| 907 |
|
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|a .b80947335
|b 03-08-23
|c 08-04-15
|
| 998 |
|
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|a web
|b 08-04-15
|c f
|d m
|e p
|f eng
|g
|h 0
|i 1
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| 956 |
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|a Information bridge
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| 999 |
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|s d04b9249-aaf7-5a6e-bc4f-b3a8ec5f0320
|
| 952 |
f |
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|p Can circulate
|a University of Colorado Boulder
|b Online
|c Online
|d Online
|e E 1.99:dp-1632
|h Superintendent of Documents classification
|i web
|n 1
|
