Advanced molecularly imprinting materials / edited by Ashutosh Tiwari and Lokman Uzun.

"Molecularly imprinted polymers (MIPs) are an important functional material because of their potential implications in diverse research fields. The materials have been developed for a range of uses including separation, environmental, biomedical and sensor applications. In this book, the chapte...

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Bibliographic Details
Online Access: Full Text (via EBSCO)
Other Authors: Tiwari, Ashutosh, 1978- (Editor), Uzun, Lokman (Editor)
Format: eBook
Language:English
Published: Hoboken, New Jersey : Beverly, Massachusetts : John Wiley & Sons, Inc. ; Scrivener Publishing LLC, [2017]
Series:Advanced materials series (Scrivener Publishing)
Subjects:

MARC

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245 0 0 |a Advanced molecularly imprinting materials /  |c edited by Ashutosh Tiwari and Lokman Uzun. 
264 1 |a Hoboken, New Jersey :  |b John Wiley & Sons, Inc. ;  |a Beverly, Massachusetts :  |b Scrivener Publishing LLC,  |c [2017] 
300 |a 1 online resource 
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490 1 |a Advanced material series 
500 |a Includes index. 
520 |a "Molecularly imprinted polymers (MIPs) are an important functional material because of their potential implications in diverse research fields. The materials have been developed for a range of uses including separation, environmental, biomedical and sensor applications. In this book, the chapters are clustered into two main sections: Strategies to be employed when using the affinity materials, and rational design of MIPs for advanced applications. In the first part, the book covers the recent advances in producing MIPs for sample design, preparation and characterizations. In the second part, the chapters demonstrate the importance and novelty of creation of recognition imprinted on the materials and surfaces for a range of microbial detection sensors in the biomedical, environmental and food safety fields as well as sensing human odor and virus monitoring systems. Part 1: Strategies of affinity materials Molecularly imprinted polymers MIP nanomaterials Micro- and nanotraps for solid phase extraction Carbonaceous affinity nanomaterials Fluorescent MIPs MIP-based fiber optic sensors Part 2: Rational design of MIP for advanced applications MIP-based biomedical and environmental sensors Affinity adsorbents for environmental biotechnology MIP in food safety MIP-based virus monitoring MIP-based drug delivery and controlled release Biorecognition imprints on the biosensor surfaces MIP-based sensing of volatile organic compounds in human body odour MIP-based microcantilever sensor system"--Provided by publisher. 
588 0 |a Print version record and CIP data provided by publisher. 
504 |a Includes bibliographical references and index. 
505 0 |a Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Part 1 Strategies of Affinity Materials -- 1 Recent Molecularly Imprinted Polymer-based Methods for Sample Preparation -- 1.1 Introduction -- 1.2 Molecularly Imprinted Solid-phase Extraction -- 1.2.1 General Considerations -- 1.2.2 Online and Inline Protocols -- 1.2.3 Improved Batch Protocols -- 1.3 Molecularly Imprinted Solid-phase Microextraction -- 1.3.1 MIP-coated Fibers -- 1.3.2 MIP Fibers (Monoliths) -- 1.4 Molecularly Imprinted Stir Bar Sorptive Extraction -- 1.5 Other Formats -- 1.5.1 Matrix Solid-phase Dispersion -- 1.5.2 Liquid Membranes and MIPs Combination -- 1.6 Conclusions -- References -- 2 A Genuine Combination of Solvent-free Sample Preparation Technique and Molecularly Imprinted Nanomaterials -- 2.1 Introduction -- 2.1.1 The Overview -- 2.1.2 General Procedure for Solid-phase Microextraction and Their Basic Components -- 2.1.3 Some Recent Examples of Solid-phase Microextraction Technique and Their Reviews -- 2.1.4 Selectivity Problem: Introduction of Molecularly Imprinted Polymer (MIP) -- 2.2 Molecularly Imprinted Polymer Modified Fiber for Solid-phase Microextraction -- 2.2.1 MISPME Using Modified Silica fiber as Stationary Phase -- 2.2.2 MISPME Using Modified Metal Fiber as Stationary Phase -- 2.2.3 Other MISPME Fibers -- 2.3 In-tube Solid-phase Microextraction Technique -- 2.4 Monolithic Fiber -- 2.5 Micro-solid-phase Extraction -- 2.6 Stir-bar Sorptive Extraction -- 2.7 Conclusion and Future Scope -- Acknowledgments -- Abbreviations -- References -- 3 Fluorescent Molecularly Imprinted Polymers -- 3.1 Introduction -- 3.2 Classes of Emitters to Endow MIPs with Fluorescence -- 3.2.1 Fluorescent Dyes -- 3.2.1.1 Changes in the Local Environment Induced by Template Rebinding -- 3.2.1.2 Hydrogen-bonding Interactions Between Template and Fluorescent Dye. 
505 8 |a 3.2.1.3 Electrostatic Interactions Between Template and Fluorescent Dye -- 3.2.1.4 Coordinative Interactions Between Template and Fluorescent Dye -- 3.2.1.5 Covalent Bonds Between Template and Fluorescent Dye -- 3.2.2 Fluorescent Probes -- 3.2.3 Lanthanide-based Systems -- 3.2.4 Quantum Dots -- 3.2.5 Carbon Dots -- 3.2.6 Upconversion Nanoparticles -- 3.3 Fluorescent Molecularly Imprinted Silica -- 3.4 Post-imprinting of MIPs -- 3.5 fMIPs as Labels -- 3.6 Formats for fMIPs -- 3.6.1 Bulk fMIPs -- 3.6.2 fMIP Films -- 3.6.3 fMIPs-containing Micro- and Nanoparticles -- 3.7 Conclusion -- References -- 4 Molecularly Imprinted Polymer-based Micro- and Nanotraps for Solid-phase Extraction -- 4.1 Introduction -- 4.2 MIPs as SPE Materials -- 4.2.1 MIP-based SPE for Environmental Samples -- 4.2.2 MIP-based SPE for Biological Samples -- 4.2.3 MIP-based SPE for Food and Beverage Samples -- 4.3 Conclusions -- References -- 5 Imprinted Carbonaceous Nanomaterials: A Tiny Looking Big Thing in the Field of Selective and Specific Analysis -- 5.1 Introduction -- 5.1.1 Popularly Used Carbon-based Nanomaterials -- 5.1.1.1 Graphene -- 5.1.1.2 Carbon Nanotubes -- 5.1.1.3 Graphene Quantum Dots/Carbon Nanodots -- 5.1.1.4 Problems in Their Use -- 5.1.2 Introduction of Molecularly Imprinted Polymers as a Selectivity Factor -- 5.1.3 Combination of MIPs and Carbonaceous Nanomaterials: Solution for Each Other -- 5.2 Graphene-modified Imprinted Polymer -- 5.2.1 Graphene-modified Imprinted Polymer in Combination with Nanoparticle -- 5.3 Carbon Nanotubes-modified Imprinted Polymer -- 5.4 Combination of Graphene, CNTs, and MIPs -- 5.5 Graphene Quantum Dots and/or Carbon Dots -- 5.6 Fullerene -- 5.7 Activated Carbon -- 5.8 Conclusions -- Acknowledgments -- List of Abbreviations -- References -- 6 Molecularly Imprinted Materials for Fiber-optic Sensor Platforms -- 6.1 Introduction. 
505 8 |a 6.1.1 General Information -- 6.1.2 General Principle of Molecular Imprinting Materials -- 6.1.2.1 Characterization of Molecularly Imprinted Polymers -- 6.1.3 General Detection Principle and Molecular Aspect of MIPs for FO Sensors -- 6.2 Material Aspect: Morphology and Physical Forms of MIPs in FO Sensors -- 6.2.1 Morphology -- 6.2.2 Physical Forms -- 6.2.2.1 Microsphere -- 6.2.2.2 Nanoparticles -- 6.2.2.3 MIPs Layers/Thin Films -- 6.3 Molecularly Imprinting Technology for Fiber-optic Sensors -- 6.3.1 General Principle of Fiber-optic Sensing -- 6.3.1.1 Extrinsic Sensing -- 6.3.1.2 Intrinsic Sensing -- 6.3.1.3 Application Areas -- 6.3.2 Sensing Functionalities and Mechanisms of Current FO Sensors -- 6.3.2.1 Fluorescence-based FOs -- 6.3.2.2 Absorption-based FOs -- 6.3.2.3 Reflectance-based FOs -- 6.3.2.4 Resonance-based Sensors -- 6.3.2.5 Classification Based on Modulation Types -- 6.3.3 Design of MIPs for Fiber-optic Sensors -- 6.3.3.1 Design Process of MIPs -- 6.3.3.2 Development and Optimization of MIPs -- 6.3.3.3 Synthesis of MIPs -- 6.3.4 Characterization Methods for MIPs -- 6.3.4.1 Chemical Characterization -- 6.3.4.2 Morphological Characterization -- 6.3.4.3 Binding Behavior Characterization -- 6.4 State-of-the-art Fiber-optic Sensors Applications Using Molecularly Imprinted Materials -- 6.5 Conclusion -- References -- Part 2 Rational Design of MIP for Advanced Applications -- 7 Molecularly Imprinted Polymer-based Sensors for Biomedical and Environmental Applications -- 7.1 Introduction -- 7.1.1 General Aspects of Molecularly Imprinting Technology -- 7.1.2 Synthesis Strategies for MIPs -- 7.1.3 MIP Polymerization Strategies -- 7.1.4 Molecular Imprinted Polymer Bonding Techniques -- 7.1.4.1 Covalent Bond Method (Pre-assembly Method) -- 7.1.4.2 Noncovalent Method (Self-assembly Method) -- 7.1.4.3 Semicovalent Imprinting. 
505 8 |a 7.1.4.4 Imprinting via Metal Coordination -- 7.1.4.5 Combinatorial Imprinting -- 7.1.5 Detection Methods for Molecularly Imprinted Polymer-based Sensors -- 7.1.5.1 Optical Detection Methods -- 7.1.5.2 Piezoelectrical Detection Methods -- 7.1.5.3 Electrochemical Detection Methods -- 7.2 Molecularly Imprinted Polymers for Analytes of Biomedical Interest -- 7.2.1 Motivation and Interest of Developing Molecularly Imprinted Polymers in the Biomedical Filed -- 7.2.2 The Pretreatment of Biological Samples When Using Molecularly Imprinted Polymer-based Sensors -- 7.2.3 Electrochemical Sensors Based on Molecularly Imprinted Polymers -- 7.2.4 Massic Sensors Based on Molecularly Imprinted Polymers -- 7.2.5 Optical Sensors Based on Molecularly Imprinted Polymers -- 7.3 Molecularly Imprinted Polymers for Analytes of Environmental Interest -- 7.3.1 Pesticides -- 7.3.2 Explosives and Warfare Agents -- 7.4 Conclusion -- Acknowledgments -- References -- 8 Molecularly Imprinted Polymers: The Affinity Adsorbents for Environmental Biotechnology -- 8.1 Introduction -- 8.2 Molecularly Imprinted Polymers -- 8.2.1 Monomers -- 8.2.2 Cross-linking Agents -- 8.2.3 Mode of Polymerization -- 8.3 Cryogels -- 8.4 Process Technology -- 8.5 Applications -- 8.5.1 Example: Capture of Compounds Binding to Estrogen Receptors -- 8.5.2 Example: Capture of Pesticides -- 8.5.3 Example: Capture of Pharmaceuticals and Their Metabolites -- 8.5.4 Example: Capture of Heavy-metal Ions -- 8.6 Elution of Captured Material -- 8.6.1 Example: MIPs as Sensing Elements in Environmental Monitoring -- 8.7 Concluding Remarks -- 8.8 Outlook -- References -- 9 Molecular Imprinting Technology for Sensing and Separation in Food Safety -- 9.1 Food Safety -- 9.2 Food Analysis -- 9.3 Current Separation Methods Used for Food Safety Purposes -- 9.4 What Is MIP? -- 9.5 MIP Applications Used for Food Safety Purposes. 
505 8 |a 9.5.1 Contaminants -- 9.5.1.1 Mycotoxins -- 9.5.1.2 Color Compounds -- 9.5.1.3 Pesticide Residues -- 9.5.1.4 Antibiotics -- 9.5.1.5 Vitamins -- 9.5.1.6 Hormones -- References -- 10 Advanced Imprinted Materials for Virus Monitoring -- 10.1 Introduction -- 10.2 Virus Imprinting -- 10.3 Artificial MIP Receptors for Viruses -- 10.4 Virus Monitoring and Detection Using Biomimetic Sensors -- 10.5 Virus Imprinting for Separation Technologies -- 10.6 Conclusions -- References -- 11 Design and Evaluation of Molecularly Imprinted Polymers as Drug Delivery Systems -- 11.1 Introduction -- 11.1.1 Drug Delivery Systems -- 11.1.2 Polymers for DDS -- 11.2 Synthesis and Characterization of MIPs Intended for Drug Release Using Non-covalent Approaches -- 11.2.1 Precipitation Polymerization -- 11.2.2 Characterization Studies -- 11.3 Design and Evaluation of Drug Delivery Systems Based on MIPs -- 11.3.1 Release Studies -- 11.3.2 Mathematical Modeling -- 11.4 Conclusions -- References -- 12 Molecularly Imprinted Materials for Controlled Release Systems -- 12.1 Introduction -- 12.2 Selectivity, Release Mechanism and Functionality of MIPs-based CR Systems -- 12.2.1 Factors That Influence the Selectivity -- 12.2.2 Recognition Characteristics of MIPs -- 12.2.2.1 Binding Site Heterogeneity -- 12.2.2.2 Restrictions on Recognition Characteristics of MIPs -- 12.2.3 Sustained-release MIP Drug Delivery Systems -- 12.2.3.1 Drug Delivery Based on Rate-programming -- 12.2.3.2 Drug Delivery Based on Activation-modulation -- 12.2.3.3 Feedback-regulated DDS -- 12.3 Molecularly Imprinted Polymers Production for Controlled Release -- 12.3.1 Synthesis and Characterization of Molecularly Imprinted Polymers -- 12.3.1.1 Synthesis Methods -- 12.3.1.2 Characterization of MIPs -- 12.3.2 Recognition Mechanisms and Types of Monomer/Template Interactions -- 12.3.2.1 Mechanism of Recognition. 
650 0 |a Molecular imprinting. 
650 0 |a Biotechnology. 
650 0 |a Bioengineering. 
650 7 |a Biotechnology  |2 fast 
650 7 |a Bioengineering  |2 fast 
650 7 |a Molecular imprinting  |2 fast 
700 1 |a Tiwari, Ashutosh,  |d 1978-  |e editor. 
700 1 |a Uzun, Lokman,  |e editor. 
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830 0 |a Advanced materials series (Scrivener Publishing) 
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