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The aqueous chemistry of the elements / George K. Schweitzer, Lester L. Pesterfield.

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Most fields of science, applied science, engineering, and technology deal with solutions in water. This volume is a comprehensive treatment of the aqueous solution chemistry of all the elements. The information on each element is centered around an E-pH diagram which is a novel aid to understanding....

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Bibliographic Details
Online Access: Full Text (via ProQuest)
Main Author: Schweitzer, George Keene, 1924-
Other Authors: Pesterfield, Lester L.
Format: Electronic eBook
Language:English
Published: Oxford ; New York : Oxford University Press, 2010.
Subjects:
Solution (Chemistry)
Inorganic compounds > Solubility.
Chemical elements > Solubility.
Table of Contents:
  • 1 E-pH Diagrams
  • 1. Introduction
  • 2. The Na E-pH Diagram
  • 3. The Al E-pH Diagram
  • 4. The Fe E-pH Diagram
  • 5. The V E-pH Diagram
  • 6. The HOH E-pH Diagram
  • 2 The Construction of E-pH Diagrams
  • 1. Introduction
  • 2. Constructing the Ga E-pH Diagram
  • 3. Constructing the Ga E-pH Diagram with Concentration Variations
  • 4. Constructing the Mn E-pH Diagram
  • 5. E-pH Computer Programs
  • 6. Species Selection and Treatment
  • 3 Reactions and Applications
  • 1. Introduction
  • 2. Reactions with HOH
  • 3. The Mn-Fe-HOH System (Excess Mn Species)
  • 4. The Mn-Fe-HOH System (Excess Fe Species)
  • 5. Combining Redox Reactions
  • 6. The HOH E-pH Diagram Revisited
  • 7. General Conclusions
  • 4 Precipitation and Complexation
  • 1. Introduction
  • 2. Precipitation and E-pH Diagrams
  • 3. Addition of Cl[sup(
  • )] to the Ag E-pH System
  • 4. Addition of S[sup( -2)] to the Zn E-pH System
  • 5. Review of Complexation and Complex Species
  • 6. Complexation and E-pH Diagrams
  • 7. Addition of Cl[sup(
  • )] to the Pd E-pH System to Form PdCl[sub(4)][sup( -2)]
  • 8. Multiple Complexes and E-pH Diagrams
  • 5 The Lithium Group
  • 1. Introduction
  • 2. Lithium (Li) 2s[sup(1)]
  • 3. Sodium (Na) 3s[sup(1)]
  • 4. Potassium (K) 4s[sup(1)]
  • 5. Rubidium (Rb) 5s[sup(1)]
  • 6. Cesium (Cs) 6s[sup(1)]
  • 7. Francium (Fr) 7s[sup(1)]
  • 8. The Ammonium Ion (NH[sub(4)][sup(+)]
  • 6 The Beryllium Group
  • 1. Introduction
  • 2. Beryllium (Be) 2s[sup(2)]
  • 3. Magnesium (Mg) 3s[sup(2)]
  • 4. Calcium (Ca) 4s[sup(2)]
  • 5. Strontium (Sr) 5s[sup(2)]
  • 6. Barium (Ba) 6s[sup(2)]
  • 7. Radium (Ra) 7s[sup(2)]
  • 7 The Boron Group
  • 1. Introduction
  • 2. Boron (B) 2s[sup(2)]2p[sup(1)]
  • 3. Aluminum (Al) 3s[sup(2)]3p[sup(1)]
  • 4. Gallium (Ga) 4s[sup(2)]4p[sup(1)]
  • 5. Indium (In) 5s[sup(2)]5p[sup(1)]
  • 6. Thallium (Tl) 6s[sup(2)]6p[sup(1)]
  • 8 The Carbon Group.
  • 1. Introduction
  • 2. Carbon (C) 2s[sup(2)]2p[sup(2)]
  • 3. Silicon (Si) 3s[sup(2)]3p[sup(2)]
  • 4. Germanium (Ge) 4s[sup(2)]4p[sup(2)]
  • 5. Tin (Sn) 5s[sup(2)]5p[sup(2)]
  • 6. Lead (Pb) 6s[sup(2)]6p[sup(2)]
  • 9 The Nitrogen Group
  • 1. Introduction
  • 2. Nitrogen (N) 2s[sup(2)]2p[sup(3)]
  • 3. Phosphorus (P) 3s[sup(2)]3p[sup(3)]
  • 4. Arsenic (As) 4s[sup(2)4p[sup(3)]
  • 5. Antimony (Sb) 5s[sup(2)]5p[sup(3)]
  • 6. Bismuth (Bi) 6s[sup(2)]6p[sup(3)]
  • 10 The Oxygen Group
  • 1. Introduction
  • 2. Oxygen (O) 2s[sup(2)]2p[sup(4)]
  • 3. Sulfur (S) 3s[sup(2)]3p[sup(4)]
  • 4. Selenium (Se) 4s[sup(2)]4p[sup(4)]
  • 5. Tellurium (Te) 5s[sup(2)]5p[sup(4)]
  • 6. Polonium (Po) 6s[sup(2)]6p[sup(4)]
  • 11 The Fluorine Group
  • 1. Introduction
  • 2. Fluorine (F) 2s[sup(2)]2p[sup(5)]
  • 3. Chlorine (Cl) 3s[sup(2)]3p[sup(5)]
  • 4. Bromine (Br) 4s[sup(2)]4p[sup(5)]
  • 5. Iodine (I) 5s[sup(2)]5p[sup(5)]
  • 6. Astatine (At) 6s[sup(2)]6p[sup(5)]
  • 12 The Scandium Group
  • 1. Introduction
  • 2. Occurrences
  • 3. Discoveries
  • 4. Scandium (Sc) 4s[sup(2)]3d[sup(1)]
  • 5. The Lanthanoids (La-Lu) 6s[sup(2)]5d[sup(0-1)]4f[sup(n)], Including Y, 5s[sup(2)]4d[sup(1)] (All Referred to as Ln)
  • 6. Actinium (Ac) 6s[sup(2)]5d[sup(1)]
  • 13 The Ti Group and the 5B, 6B, 7B and 8B Heavy Elements
  • 1. General Introduction
  • 2. Introduction to the Insoluble-oxide Elements: Ti, Zr, Hf, Nb, Ta
  • 3. Titanium (Ti) 4s[sup(2)]3d[sup(2)]
  • 4. Zirconium (Zr) 5s[sup(2)]4d[sup(2)] and Hafnium (Hf) 6s[sup(2)]5d[sup(2)]
  • 5. Niobium (Nb) 5s[sup(2)]4d[sup(3)]
  • 6. Tantalum (Ta) 6s[sup(2)]5d[sup(3)]
  • 7. Introduction to the High Oxidation State Oxyanion Elements: Mo, W, Tc, Re
  • 8. Molybdenum (Mo) 5s[sup(1)]4d[sup(5)]
  • 9. Tungsten (W) 6s[sup(1)]5d[sup(5)]
  • 10. Rhenium (Re) 6s[sup(2)]5d[sup(5)]
  • 11. Technetium (Tc) 5s[sup(2)]4d[sup(5)].
  • 12. Introduction to the Noble Metal Elements: Ru, Rh, Pd, Os, Ir, Pt
  • 13. Ruthenium (Ru) 5s[sup(1)]4d[sup(7)]
  • 14. Osmium (Os) 6s[sup(2)]5d[sup(6)]
  • 15. Rhodium (Rh) 5s[sup(1)]4d[sup(8)]
  • 16. Iridium (Ir) 6s[sup(2)]5d[sup(7)]
  • 17. Palladium (Pd) 5s[sup(0)]4d[sup(10)]
  • 18. Platinum (Pt) 6s[sup(1)]5d[sup(9)]
  • 14 The V-Cr-Mn Group
  • 1. Introduction
  • 2. Vanadium (V) 4s[sup(2)]3d[sup(3)]
  • 3. Chromium (Cr) 4s[sup(1)]3d[sup(5)]
  • 4. Manganese (Mn) 4s[sup(2)]3d[sup(5)]
  • 15 The Fe-Co-Ni Group
  • 1. Introduction
  • 2. Iron (Fe) 4s[sup(2)]3d[sup(6)]
  • 3. Cobalt (Co) 4s[sup(2)]3d[sup(7)]
  • 4. Nickel (Ni) 4s[sup(2)]3d[sup(8)]
  • 16 The Cu Group
  • 1. Introduction
  • 2. Copper (Cu) 4s[sup(1)]3d[sup(10)]
  • 3. Silver (Ag) 5s[sup(1)]4d[sup(10)]
  • 4. Gold (Au) 6s[sup(1)]5d[sup(10)]
  • 17 The Zn Group
  • 1. Introduction
  • 2. Zinc (Zn) 4s[sup(2)]3d[sup(10)]
  • 3. Cadmium (Cd) 5s[sup(2)]4d[sup(10)]
  • 4. Mercury (Hg) 6s[sup(2)]5d[sup(10)]
  • 18 The Actinoid Metals
  • 1. Introduction
  • 2. Availabilities of the Elements
  • 3. Discoveries and Extractions
  • 4. Elements and Compounds
  • 5. E-pH Diagrams
  • 6. Complexes
  • 7. Trans-lawrencium Elements
  • References
  • Index
  • A
  • B
  • C
  • D
  • E
  • F
  • G
  • H
  • I
  • L
  • M
  • N
  • O
  • P
  • R
  • S
  • T
  • U
  • V
  • W
  • Y
  • Z.

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