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Redox-active ligands : concepts and catalysis / edited by Marine Desage-El Murr.

Redox-Active Ligands Authoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesi...

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Bibliographic Details
Online Access: Full Text (via Wiley)
Other Authors: Desage-El Murr, Marine (Editor)
Format: Electronic eBook
Language:English
Published: Weinheim, Germany : Wiley-VCH, 2024.
Subjects:
Ligands.
Oxidation-reduction reaction.
Table of Contents:
  • Preface
  • Part I Introduction and Concepts
  • 1 Anatomy of a Redox-Active Ligand 3 Marine Desage-El Murr
  • 1.1 Introduction
  • 1.2 Biological Inspiration: From the Enzyme to the Flask, a Continued Journey
  • 1.3 Chemical History: Puzzle-Solving for Coordination Chemists
  • 1.4 Combining Spectroscopy and Theory: How to Spot a Redox-Active Ligand?
  • 1.5 Non-innocent, Cooperative, Electro-Active, or Redox-Active?
  • 1.6 Unusual Ligands and Unusual Reactivities with a Redox-Active Ligand
  • 1.7 Perspectives and Concluding Remarks
  • 2 Mechanistic Studies of Catalytic Nitrene-Transfer Reactions Involving Redox-Active Ligands and Substrates 21 Nicolaas P. van Leest, Jarl Ivar van der Vlugt, and Bas de Bruin
  • 2.1 Introduction
  • 2.2 Characterization of Radical-type Intermediates
  • 2.3 Mechanistic Studies
  • 2.4 Case Studies for Nitrene Transfer Aided by Redox-Active Ligands and Substrates
  • 3 Redox-Active Ligands From a Computational Perspective 53 Roy Eckhardt, Dorys Reyes, Christian Sandoval-Pauker, and Balazs Pinter
  • 3.1 Introduction
  • 3.2 Electronic Structure Determination Through DFT and Spectroscopy
  • 3.3 Redox-Active Ligands as Electron Reservoirs
  • 3.4 In Silico Description and Engineering of Redox-Active Ligands
  • 3.5 Conclusions
  • Part II Applications
  • 4 Complexes of Stable N-aryl Radicals and Their Catalytic Applications 109 Nicolas Leconte and Fabrice Thomas
  • 4.1 Introduction and General Considerations on Exocyclic N-aryl Radicals
  • 4.2 Complexes Featuring Anilinyl Radicals
  • 4.3 Bidentate o-diaminobenzenes and Their Radicals
  • 4.4 Pincer Ligands and Their Radicals
  • 4.5 Branched Tetradentate o-diaminobenzene and Associated Radicals
  • 4.6 Polydentate Ligands Featuring One Bidentate Diiminosemiquinone Radical
  • 4.7 Representative Catalytic Applications
  • 4.8 Conclusion
  • 5 Redox-Active Ligands in Coordination Chemistry and Organic Synthesis 151 Toru Amaya, Toshiyuki Moriuchi, and Toshikazu Hirao
  • 5.1 Introduction
  • 5.2 Controlled Formation of Conjugated Complexes with Redox-Active Polyanilines or 1,4-Benzoquinonediimines
  • 5.3 Catalytic Application of Hybrid Systems Consisting of Redox-Active Polyanilines and Transition Metals
  • 5.4 Conclusion
  • 6 Metal Complexes Bearing Redox-Active Supporting Ligands that Promote Chemical Transformations Involving Protons and Electrons 175 Kundan K. Singh and Isaac Garcia-Bosch
  • 6.1 Introduction
  • 6.2 Dioxygen Reduction toWater
  • 6.3 Dioxygen Reduction Coupled with Substrate Dehydrogenation
  • 6.4 Dioxygen Reduction Coupled with Substrate Hydroxylation
  • 6.5 Conclusions and Future Perspectives
  • Part III Case Studies
  • 7 Redox-Active Guanidine Ligands 199 Hans-Jörg Himmel
  • 7.1 Introduction
  • 7.2 Properties and Reactivity of Uncoordinated Redox-Active Guanidines
  • 7.3 Redox-Active Guanidines as Ligands in Coordination Chemistry
  • 7.4 Perspectives
  • 8 Coordination Chemistry with Lanthanides and Redox-Active Ligands 249 Valeriu Cemortan and Grégory Nocton
  • 8.1 Introduction
  • 8.2 Quinone, Iminoquinone, and O-phenylenediamine-Based Complexes
  • 8.3 Diazadienes
  • 8.4 Iminopyridines and Bis(imino)pyridines
  • 8.5 Nitroxides
  • 8.6 N-heterocycles
  • 8.7 Conclusion and Outlook
  • 9 Actinide Complexes of Redox Non-innocent Ligands 317 Karlotta van Rees and Jason B. Love
  • 9.1 Bipyridyl Ligands
  • 9.2 Pyrrole Ligands
  • 9.3 Tmtaa Ligand
  • 9.4 Schiff-Base Ligands
  • 9.5 Pyridine(di-imine) Ligands
  • 9.6 Phosphite Ligands
  • 9.7 Quinone Ligands
  • 9.8 Aryloxide Ligands
  • 9.9 Conclusion
  • References
  • Index.

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